Molecular Design of Luminescent Gold(III) Emitters as Thermally Evaporable and Solution-Processable Organic Light-Emitting Device (OLED) Materials.

The advancement of high-efficiency luminescent and thermally stable organometallic complexes has offered opportunities for the commercialization of metal phosphors for fabricating organic light-emitting devices (OLEDs). Since the first report on the potential use of iridium(III) and platinum(II) complexes for applications in OLEDs in the late 1990s, extensive efforts have been made by researchers on the development of various heavy metal-containing compounds with rich photophysical and luminescence properties and the engineering of device architectures to improve device efficiencies. Apart from the more well-studied iridium(III) and platinum(II) complexes, complexes of gold(III) recently have demonstrated their capabilities to serve as phosphorescent or thermally stimulated delayed phosphorescent or thermally activated delayed fluorescent emitters, and their promising performances in OLEDs have attracted growing interest in the past decade. Nowadays, complexes of gold(III) with emission energies ranging from sky-blue to near-infrared with high electroluminescence performances have been obtained. In addition, high-efficiency vacuum-deposited and solution-processed OLEDs with benchmark efficiencies comparable to those of the iridium(III) and platinum(II) complexes have been realized. This Focus Review summarizes the development of various series of luminescent gold(III) complexes to date and highlights important milestones in the development and advancement of gold(III)-based OLEDs. Focus will be made on the molecular design strategies for gold(III) emitters for application as dopants in OLEDs, including those fabricated by vacuum-deposition and solution-processing techniques.