Literature DB >> 34139121

Isolable Pyridinium Trifluoromethoxide Salt for Nucleophilic Trifluoromethoxylation.

Geraldo Duran-Camacho1, Devin M Ferguson1, Jeff W Kampf1, Douglas C Bland2, Melanie S Sanford1.   

Abstract

An isolable pyridinium trifluoromethoxide salt is prepared from the reaction of 4-dimethylaminopyridine with the commercially available liquid 2,4-dinitro(trifluoromethoxy)benzene. The salt is an effective trifluoromethoxide source for SN2 reactions to form trifluoromethyl ethers.

Entities:  

Year:  2021        PMID: 34139121     DOI: 10.1021/acs.orglett.1c01664

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Halogenation Reactions of Alkyl Alcohols Employing Methyl Grignard Reagents.

Authors:  Nadia Hirbawi; Patricia C Lin; Elizabeth R Jarvo
Journal:  J Org Chem       Date:  2022-09-01       Impact factor: 4.198

  1 in total

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