MXenes for Solar Cells.

Application of two-dimensional MXene materials in photovoltaics has attracted increasing attention since the first report in 2018 due to their metallic electrical conductivity, high carrier mobility, excellent transparency, tunable work function and superior mechanical property. In this review, all developments and applications of the Ti3C2Tx MXene (here, it is noteworthy that there are still no reports on other MXenes' application in photovoltaics by far) as additive, electrode and hole/electron transport layer in solar cells are detailedly summarized, and meanwhile, the problems existing in the related studies are also discussed. In view of these problems, some suggestions are given for pushing exploration of the MXenes' application in solar cells. It is believed that this review can provide a comprehensive and deep understanding into the research status and, moreover, helps widen a new situation for the study of MXenes in photovoltaics.

Introduction

With the ever-increasing demand of clean and renewable energy resources [1-4], considerable attention has been devoted to the development of novel materials toward efficient solar cells [5-14]. As a family of important two-dimensional materials, MXenes, layered carbides and nitrides of transition metals first reported by the Gogotsi group in 2011 [15], which have been extensively investigated in various fields including energy storage [16-22], biomedical fields [23-25], electromagnetic applications [26-29], sensors [30-34], light-emitting diodes [35-37], water purification [38-43] and catalysis [44-47], have exhibited promising application in solar cells very recently. Among various MXenes, Ti3C2T (T represents some surface-terminating functional groups such as –O, –OH and –F) dominates the present study of MXenes in solar cells because of its high electrical conductivity and carrier mobility, excellent transparency and tunable work function (WF) [48-50]. Since the first report of Ti3C2T as an additive in the photoactive layer of MAPbI3 (MA: CH3NH3)-based perovskite solar cells (PSCs) in 2018 [51], its application has been extended to electrode, hole/electron transport layer (HTL/ETL), additive in HTL/ETL and the component of forming the Schottky junction-based solar cells with silicon (Si) wafers, etc.

To comprehensively understand the achievements and meanwhile to provide insights and valuable suggestions for the following development, a timely summary and discussion of the related studies is highly necessary. In this review, we first categorize the roles of Ti3C2T played in the reported solar cells and then follow the roles to introduce the achievements and analyze the existing problems limiting device performance improvement. Finally, a perspective to outlook the further development of the MXenes’ application in solar cells is given.

As summarized in Fig. 1, the roles of the Ti3C2T MXene in application of solar cells can be categorized into three kinds, i.e., additive [51], electrode [52] and HTL/ETL [53]. In the meantime, the corresponding type of the solar cells is also summarized for each role played by Ti3C2T. Moreover, it is noted that the corresponding areas of the roles and the solar cells in Fig. 1 are in direct proportion to the number of the reports/publications. One thus can conclude that the Ti3C2T MXene is mainly applied in perovskite and organic solar cells (OSCs). In the following part, the review will be extended following the role of the Ti3C2T MXene.

Fig. 1

Roles of the Ti3C2T MXene played in application of varying solar cells. The areas correspond to the publication numbers for each application

Applications of MXenes in Solar Cells

Additive in Perovskite Materials, ETLs/HTLs

In 2018, Guo et al. first reported addition of Ti3C2T into the MAPbI3-based perovskite absorber [51], initiating exploration of the MXenes’ application in solar cells. Their study indicates that addition of Ti3C2T can retard the nucleation process of MAPbI3 (see the schematic diagram in Fig. 2a), resulting in the enlarged crystal size. Moreover, the Ti3C2T additive is highly beneficial to accelerate the electron transfer, like a “carrier bridge” [54-57], through the grain boundary, which is further confirmed by the lower charge transfer resistance for the Ti3C2T-added device as indicated by the electrochemical impedance spectra exhibited in Fig. 2b. Thanks to these effects, the average power conversion efficiency (PCE) increases from 15.18% to 16.80%. (Note: all PCEs in this review were measured at AM 1.5G illumination.)

Fig. 2

a Nucleation and growth routes of the MAPbI3-based perovskite films with and without adding the Ti3C2T MXene. b Nyquist plots of the PV devices with and without 0.03 wt% Ti3C2T addition measured in the dark with a bias of 0.7 V.

Copyright © 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. c Schematic illustration of the preparation process of surface-decorated MAPbBr3 nanocrystals by few-layer Ti3C2T MXene nanosheets, i.e., MAPbBr3/Ti3C2T heterostructures. d Energy-level alignment and electron transfer between the MAPbBr3 crystals and the coated Ti3C2T nanosheets. Copyright © 2020 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. e Device architecture and cross-sectional scanning electron microscopy (SEM) image, and f energy-level alignment of the perovskite solar cell with the embedded ultrathin Ti3C2T quantum dots in the perovskite layer and the ETL/TiO2 interface and Cu1.8S in the Spiro-OMeTAD HTL. Copyright © 2020 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

In 2019, Agresti et al. reported the WF adjustment of the MAPbI3 films and thus optimization of the energy-level alignment for improving the performance of the related solar cells by adding the Ti3C2T MXene [58]. It was found that the WF of the perovskite films could be effectively tuned from 4.72 to 4.37 eV without affecting other intrinsic electronic properties such as bandgap, the relative position of the valance band to the Fermi level and film morphology. The PCE of the Ti3C2T-incorporated MAPbI3-based solar cells can be improved by 26.5% after simultaneously introducing Ti3C2T addition in the ETL, as compared to the control one without Ti3C2T. Recently, Zhang et al. reported surface decoration of MAPbBr3 nanocrystals by few-layer Ti3C2T MXene nanosheets to form the perovskite/MXene heterostructure via in situ solution growth, as shown in Fig. 2c [59]. The facilitated electron injection from the MAPbBr3 nanocrystals to the Ti3C2T MXene because of the matched energy levels, as indicated in Fig. 2d, is beneficial to performance improvement for the related solar cells.

Very recently, Chen et al. first reported employment of ultrathin Ti3C2T quantum dots (TQDs) to engineer the CsFAMA (FA: CH(NH2)2) perovskite absorber and the perovskite/TiO2 ETL interface, as indicated in Fig. 2e [60]. Thanks to the improved crystallinity of the perovskite film and the matched energy-level alignment (Fig. 2f) and thus the enhanced electron extraction at the perovskite/TiO2 ETL interface, the solar cell delivers a remarkable hysteresis-free PCE of 20.72% compared with 18.31% for the reference device and long-time ambient and light stability. It is notable that the improved performance and stability are also partly contributed by the addition of Cu1.8S in the HTL facilitating the perovskite crystallinity and the increased hole extraction at the perovskite/Spiro-OMeTAD HTL interface because of the matched energy-level alignment, as indicated in Fig. 2f.

Besides addition in the active layer, embedding the Ti3C2T MXene in ETLs/HTLs has also been reported. In 2019, Yang et al. reported modification of the SnO2 ETL by adding 1.0 wt‰ Ti3C2T for the MAPbI3-based PSCs (Fig. 3a, b for the schematized architecture and cross-sectional SEM image of the device). Thanks to the facilitated electron transport and enhanced hole blocking because of the optimized energy-level alignment due to Ti3C2T addition (Fig. 3c), PCE increases to 18.34% from 17.23% for the control device without Ti3C2T addition [61]. Huang et al. further advanced the Ti3C2T MXene-added SnO2 ETL by introducing TiO2 with a suitable crystal phase for forming an effective heterojunction structure, named a multi‑dimensional conductive network (MDCN) structure, as exhibited in Fig. 3d, e. Owing to the matched energy-level alignment (Fig. 3f) of the ETL with the (FAPbI3)0.97(MAPbBr3)0.03 photoactive and FTO transparent conductive layers, a PCE increment from 16.83% (SnO2 ETL) to 19.14% is achieved. Moreover, the MDCN-incorporated device exhibits high toleration to moisture and maintains ~ 85% of the initial performance for more than 45 days in 30–40% humidity air due to an oxygen vacancy scramble effect [62].

Fig. 3

a Device architecture, b cross-sectional SEM image and c schematic energy-level diagram of each component for the PV device of ITO/Ti3C2T MXene-added SnO2 ETL/MAPbI3/Spiro-OMeTAD/Ag.

Copyright © 2019 The Royal Society of Chemistry. d Device architecture, e cross-sectional SEM image and f schematic energy-level diagram of each component for the PSCs using MDCN as the ETL

Besides modification of the MAPbI3 photoactive layer using Ti3C2T, Agresti et al. also incorporated Ti3C2T into the TiO2 ETL to finely tune its WF, i.e., from 3.91 to 3.85 eV that benefits for tuning the interface energy-level alignment between the perovskite absorber and the TiO2 ETL, thus reducing the barrier height and enhancing charge transfer [58]. Based on dual addition and optimization in both the MAPbI3 photoactive and TiO2 electron transport layers, the device delivers a PCE of 20.14%, ~ 26.5% higher than that of the control device without Ti3C2T addition. Moreover, it was found that the Ti3C2T addition reduces hysteresis in the current density–voltage (J–V) curves and meanwhile enhances long-time exposure stability of the PSCs. Very recently, this group further investigated the MAPbI3 perovskite/Ti3C2T-based MXene interface using density functional theory calculations, and the results show that the interface WF exhibits a strong nonlinear behavior when the relative concentrations of OH-, O- and F-terminating groups are varied, providing a deep insight regarding the energy-level alignment for high-performance device fabrication [63].

Similarly, adding the Ti3C2T MXene into HTLs also can improve device performance. Recently, Hou et al. reported modification of the conductive polymer, PEDOT:PSS (poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)), normally as the HTL in OSCs using the Ti3C2T MXene nanosheets [64]. As demonstrated in Fig. 4a, after adding the MXene nanosheets, more charge transfer channels between PEDOT nanocrystals can be formed. In the meantime, the conformational transformation of PEDOT from a coil structure to a linear/expansion coil structure can be induced, hence leading to the improved electrical conductivity for the modified PEDOT:PSS, as verified by the conductivity measurement shown in Fig. 4b. Using the modified PEDOT:PSS as the HTL, the OSCs based on the non-fullerene PBDB-T:ITIC system were constructed, as schematized in Fig. 4c. Thanks to the improved electrical conductivity and matched energy-level alignment with the neighboring components (Fig. 4d) for the Ti3C2T-modified PEDOT:PSS, a PCE of 11.02% is achieved as compared to 9.72% for the control device using pure PEDOT:PSS as the HTL. When using the PM6:Y6 system as the active layer, a PCE of 14.55% can be delivered for the case of employing the Ti3C2T-modified PEDOT:PSS HTL as compared to 13.10% for the control device using pure PEDOT:PSS. Moreover, appropriate addition of the Ti3C2T MXene nanosheets can improve the performance stability, as indicated in Fig. 4e.

Fig. 4

a Schematic illustration of morphological and structural modification in PEDOT:PSS with incorporation of the Ti3C2T MXene nanosheets. b Electrical conductivity of PEDOT:PSS with varying Ti3C2T additions on bare glass. c Device configuration and d energy-level diagram of each component for the OSC using Ti3C2T-modified PEDOT:PSS as the HTL. e Stability test for the devices with varying Ti3C2T additions based on the PBDB-T:ITIC photoactive layer measured in a N2 glove box.

Copyright © The Royal Society of Chemistry. f Device configuration and g energy-level diagram of each component for the OSC using ZnO/Ti3C2T as the ETL. h Stability test of the devices based on the PBDB-T:ITIC photoactive with varying Ti3C2T additions without encapsulation in air. Copyright © 2020 Elsevier B.V

Moreover, they also tried to add the Ti3C2T MXene nanosheets in zinc oxide (ZnO) to fabricate a novel ZnO/Ti3C2T hybrid ETL by precisely controlling the amount of Ti3C2T in the sol–gel ZnO precursor solution [65]. The nanosheets act as the “electron bridges,” as aforementioned [54, 55], between the ZnO nanocrystals, thus providing additional charge transport pathways. Meanwhile, the Ti3C2T MXene passivates the surface of the ZnO nanocrystals by forming the Zn–O–Ti bonding, through which electrons can transfer. This ZnO/Ti3C2T hybrid ETL with excellent optical and electrical properties was applied in fullerene (PBDB-T:ITIC and PM6:Y6) and non-fullerene (PTB7:PC71BM) OSCs (Fig. 4f, g for the architecture and energy-level alignment of the device), and the improved PCEs of 12.20%, 16.51% and 9.36% from 10.56%, 14.99% and 8.18% for the control devices using the pristine ZnO ETLs were achieved by the solar cells based on the PBDB-T:ITIC, PM6:Y6 and PTB7:PC71BM photoactive layers, respectively. Moreover, the improved stability for the devices using the ZnO/Ti3C2T hybrid ETLs was observed, as shown in Fig. 4h.

Electrode

The newly reported electrical conductivity of the Ti3C2T MXene has reached as high as 15,100 S cm–1 [66], and moreover, high transparency, outstanding flexibility and adjustable WF are associated with it [67-69]. All these properties make Ti3C2T suitable as electrodes in optoelectronic devices including solar cells. In the following, the review will be expanded in the sequence of the perovskite-based, organic, Si wafer-based and dye-sensitized solar cells.

In 2019, Gao et al. reported use of Ti3C2T MXene materials as the back electrode in noble-metal-free MAPbI3-based PSCs through a simple hot-pressing method, and Fig. 5a–c shows the preparation procedure, cross-sectional SEM image and energy-level alignment of each component for the devices [52]. One notes that as the back electrode, the Ti3C2T MXene can facilitate hole injection from the MAPbI3 photoactive layer, and the device delivers a PCE of up to 13.83%, ~ 27.2% higher than that of the control device using the carbon electrode. Moreover, thanks to the seamless interfacial contact, the device exhibits improved stability compared with the control one. Recently, Mi et al. employed a mixed electrode consisting of carbon, carbon nanotube (CNT) and Ti3C2T in CsPbBr3-based PSCs, and Fig. 5d shows the device architecture and the cross-sectional SEM images of the mixed electrode. As indicated in Fig. 5e, the devices using the Ti3C2T-incorporated electrodes exhibit improved performance compared with the devices employing the electrodes without Ti3C2T [70].

Fig. 5

a Fabrication process of the MAPbI3-based PSCs with a Ti3C2T back electrode prepared using a hot-pressing method. b Cross-sectional SEM image and c energy-level alignment of each component for the MAPbI3-based PSCs.

Copyright © 2019 The Royal Society of Chemistry. d Device configuration of the CsPbBr3-based solar cells using the mixed carbon electrode and cross-sectional SEM images of the mixed carbon electrode. e Illuminated J–V curves of the solar cells with different types of electrodes. Copyright © 2020 The Royal Society of Chemistry

In 2019, Tang et al. combined Ti3C2T nanosheets with Ag nanowire networks to fabricate the transparent, highly conductive and flexible hybrid electrodes for flexible OSCs that are based on different combinations of organic active materials including PTB7-Th:PC71BM, PBDB-T:ITIC and PBDB-T:ITIC:PC71BM [71]. This MXene/Ag nanowire hybrid electrode, prepared via a simple and scalable solution-processed method as shown in Fig. 6a, exhibits excellent performance. The flexible ternary (PBDB-T:ITIC:PC71BM) OSCs using this hybrid transparent electrode deliver a champion PCE of 8.30% and meanwhile exhibit robust mechanical performance, i.e., 84.6% retention of the initial PCE after 1000 bending and unbending cycles to a 5-mm bending radius.

Fig. 6

a Fabrication process of the flexible transparent electrodes based on Ti3C2T MXene nanosheets and Ag nanowire networks.

Copyright © 2019 American Chemical Society. b Schematic of the preparation (left), optical photograph (upper right) and cross-sectional demonstration (lower right) of the Ti3C2T transparent flexible electrode for the PV supercapacitors. c Working principle of the semitransparent, flexible PV supercapacitor in the charge (left) and discharge states. Copyright © 2020 The Royal Society of Chemistry

Recently, Qin et al. reported utilization of the Ti3C2T MXene thin film as a common electrode to fabricate the MXene-based all-solution-processed semitransparent flexible photovoltaic (PV) supercapacitor by integrating a flexible OSC and a transparent MXene supercapacitor in the vertical direction [72]. Figure 6b shows the schematic of the preparation (left), optical photograph (upper right) and cross-sectional demonstration (lower right) of the transparent flexible electrode, and the device configuration and working principle are shown in Fig. 6c. The flexible OSCs with Ti3C2T as the transparent electrode can deliver a high PCE of 13.6%, comparable with that of the control device using an ITO electrode. The PV supercapacitor exhibits an average visible transmission of 33.5% and the maximum storage efficiency and overall efficiency of up to 88% and 2.2%, respectively. In addition, this strategy is suitable for blading, printing and roll-to-roll manufacturing, which is promising for the production of cost-efficient flexible PV supercapacitors to satisfy the increasing energy demands for portable, wearable and miniature electronic devices.

In 2019, Fu et al. drop-casted the Ti3C2T MXene solution on the groove surface of the n+-Si emitter as the back electrode in an n+–n–p+ Si solar cell (see Fig. 7a–c for the device architecture, groove surface before and after MXene coating) [73]. The ohmic contact between Ti3C2T and n+-Si (see Fig. 7d for the energy-level alignment) facilitates electron transfer from the n+-Si emitter and thus suppresses charge carrier recombination, resulting in good output of the short-circuit current density (Jsc) and open-circuit voltage (Voc). Moreover, it was found that the rapid thermal annealing (RTA) treatment of 30 s can further improve the electrical contact and physical adhesion between the MXene coating and the n+-Si substrate, leading to the reduced series resistance (it can be concluded from the increased slope for the J–V curves around Voc in Fig. 7e and also verified by the resistance measurement, as exhibited in Fig. 7f) and thus a remarkable improvement of PCE to 11.5%. In some cases, MXenes serve both the electrode and the component of forming the Schottky junction with Si. For example, Yu et al. reported a Schottky junction solar cell fabricated based on Ti3C2T and n-Si, where the Ti3C2T electrode meanwhile serves as a transparent conducting film for charge collection, as shown in Fig. 10a (later) [74]. For this content, we would like to more detailedly discuss in the following part of MXenes as HTLs/ETLs.

Fig. 7

a Schematic illustration for the n+–p–p+ Si solar cell using the Ti3C2T MXene as the electrode contacted with the n+ emitter. SEM images of grooves on the n+ side surface b before and c after MXene coating. d Energy-level alignment. Φ is a work function; Eg, Ec and Ev are the energy bandgap, conduction band and valence band of Si. e Illuminated J-V curves before and after 30 s RTA treatment at varying temperatures. f Series resistance values deduced from the J–V measurement for the samples before and after the RTA process.

Copyright © 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

Fig. 10

Ti3C2T MXene/n-Si solar cells: a Energy-level alignment of the main components (the blue strip indicates the SiO2 thin layer), b illuminated J–V curves for the devices fabricated via floating and oven transfer methods and c illuminated J–V curves for the devices fabricated by the oven transfer method and after the two-step (HCl + AuCl3) chemical treatment and further coating the PDMS antireflection film.

Copyright © 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

The Ti3C2T MXene was also employed to fabricate the counter electrode (CE) in quantum dot-sensitized solar cells (QDSCs). In 2019, Chen et al. reported a composite CE consisting of hydrothermally grown CuSe nanoparticles on Ti3C2T MXene nanosheets that were screen-printed onto a graphite sheet [75]. This composite CE possesses the better electrical conductivity for electron transfer and a larger specific surface area to provide more active sites for polysulfide electrolyte reduction, as compared to CuSe- and Ti3C2T-based CEs, respectively. The PCE of 5.12% can be achieved by the device using the CuSe/Ti3C2T composite CE with an optimal mass ratio. As a comparison, the devices using the CuSe- and Ti3C2T-based CEs deliver the PCE of 3.47% and 2.04%, respectively. Similarly, Tian et al. fabricated the CuS/Ti3C2 composite CEs via a facile ion-exchange method at room temperature, exhibiting a significantly faster electrocatalytic rate toward the polysulfide reduction than pure CuS [76]. The QDSC based on this composite CE delivers an overall PCE of 5.11%, which is 1.5 times obtained from the device using the pure CuS CE. The performance enhancement is mainly attributed to the combined advantages of the excellent conductivity of the Ti3C2 skeleton and the abundant catalytically active sites of the CuS nanoparticles.

HTL/ETL

Owing to the easily tunable WF, the Ti3C2T MXene can also be applied as an HTL or ETL, and the related reports in PSCs, OSCs and crystalline Si solar cells can be found. In 2019, Chen et al. reported insertion of Ti3C2T nanosheets between the CsPbBr3 active layer and the carbon electrode as the HTL [77], as indicated in Fig. 8a. The electron potential barrier because of the inserted Ti3C2T layer (Fig. 8b, c) effectively blocks the transfer of electrons from CsPbBr3 to the carbon electrode and thus mitigates the electron–hole recombination. In addition, the CsPbBr3 grains can be well passivated by the functional groups in Ti3C2T, thus reducing the trap defects in the CsPbBr3 film and improving the perovskite film quality. A high initial PCE of 9.01% is obtained for the PSCs with long-term stability for more than 1900 h in a moisture environment and over 600 h under thermal conditions.

Fig. 8

CsPbBr3-based PSCs using the Ti3C2T nanosheet layer as the HTL: a Cross-sectional SEM image, b energy-level alignment and c carrier transport mechanism at illumination.

Copyright © 2019 The Royal Society of Chemistry. d Device architecture and e cross-sectional SEM image, f energy-level alignment of each layer. Copyright © 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. g Device configuration and h energy-level alignment of the device. i Cross-sectional SEM image of the device (left), first-principle optimized structures and electron density differences for SnO2/Ti3C2(OH)2 (upper right), and spatially resolved mapping of the current transport efficiency of the MXene-inserted device (lower right). Copyright © 2020 American Chemical Society

In the same year, employing the Ti3C2T layer as a novel ETL for MAPbI3-based PSCs was reported by Yang et al. [78], and Fig. 8d, e shows the device architecture and cross-sectional SEM image of the solar cell. Under the assistance of ultraviolet–ozone (UV–O3) treatment, the Fermi level of Ti3C2T could be downshifted from − 5.52 to − 5.62 eV, as indicated in Fig. 8f, and meanwhile, the interface properties between Ti3C2T and MAPbI3 were improved because of the formation of the additional oxide-like Ti–O bonds on the surface of Ti3C2T (Ti3C2O2). Thanks to the enhanced hole blocking because of the downshifted Fermi level of Ti3C2T and meanwhile to the improved MAPbI3/Ti3C2T interface, a champion PCE of 17.17% was thus achieved for the device employing the Ti3C2T MXene film with 30 min UV–O3 treatment. However, the device using Ti3C2T without UV–O3 treatment only delivers the 5.00% PCE. Further investigations verified that the charge transfer was truly enhanced for the case with the optimal UV–O3 treatment of 30 min, as indicated by the EIS measurement. In addition, UV–O3 treatment to Ti3C2T also contributes to improve the device stability.

Recently, Wang et al. reported a perovskite solar cell with a thin Ti3C2T MXene layer inserted between the F-doped SnO2 (FTO) electrode and the SnO2 ETL [79], and Fig. 8g, i shows the architecture and cross-sectional SEM image of the device. As indicated in Fig. 8h, the inserted MXene thin layer is favorable to form matched energy-level alignment between FTO and the SnO2 ETL, thus facilitating electron transport from SnO2 to FTO. Meanwhile, the strong interaction and electron hybridization between MXene and SnO2 can be introduced (see Fig. 8i for the simulated structure), thus leading to the enhanced electron mobility in SnO2. Moreover, the surface of the SnO2 ETL becomes more hydrophobic and smoother than the case without MXene, which is beneficial for growing high-quality perovskite layers. It was also found that compared with the case without MXene, non-radiative recombinations were significantly suppressed by the MXene-modified SnO2 ETL together with the remarkably improved homogeneity and reduced carrier transport loss (Fig. 8i). Thanks to these synergetic effects introduced by the MXene thin layer, the related device delivers a stabilized PCE of 20.65% (< 19.00% for the control device without MXene) with an ultralow saturated current density and negligible hysteresis.

In 2019, Yu et al. reported utilization of the UV–O3 treatment or N2H4 treatment to increase or decrease the WF of Ti3C2T (in a range between 4.08 and 4.95 eV) because of the oxidation or reduction of the C element, respectively [53]. As shown in Fig. 9a, the Ti3C2T MXenes with different WFs can be used as either the HTLs or ETLs for the OSCs employing PBDB-T:ITIC as the photoactive layer. The PCEs of 9.06% and 9.02% were obtained for the cases using Ti3C2T as electron and hole-collection buffer layers, respectively (Fig. 9b). Moreover, it was found that Voc increases with the treatment duration, as exhibited in Fig. 9c. In the same year, Hou et al. also reported employment of Ti3C2T as the HTLs in PBDB-T:ITIC-based OSCs to facilitate hole transport and collection, benefiting from the outstanding metallic conductivity of Ti3C2T, improved interface contact and matched energy-level alignment as exhibited in Fig. 9d [80]. It is notable that evident enhancement of PCE can be achieved for the devices using Ti3C2T as the HTLs compared with the control one only using ITO (PCE: 4.21%). Moreover, the optimal Ti3C2T-based device also outperforms the state-of-the-art PEDOT:PSS-based device, i.e., 10.53% vs. 10.11% (see Fig. 9e for the device performance comparison). Meanwhile, the Ti3C2T-based devices also exhibit the improved long-term stability under the atmosphere condition without any encapsulations, as indicated in Fig. 9f.

Fig. 9

PBDB-T:ITIC-based OSCs using the UV–O3 and/or N2H4-treated Ti3C2T MXene as the ETL/HTL: a Energy levels of the main components and b illuminated J–V curves of the PBDB-T:ITIC-based OSCs. Here, U-MXene and UH-MXene denote the MXene treated only by UV–O3, and first by UV–O3 and then by N2H4, respectively. Moreover, U-MXene is used for the hole collection in the normal OSCs, and the UH-MXene is for the electron collection in the inverted OSCs; and c Voc versus the treatment duration.

Copyright © 2019 The Royal Society of Chemistry. PBDB-T:ITIC-based OSCs using Ti3C2T nanosheets as the HTL: d Energy-level alignment of each component, e illuminated J–V curves, and f stability test under the atmosphere condition without any encapsulations. Copyright © 2019 The Royal Society of Chemistry

As briefly aforementioned, in 2019, Yu et al. reported a novel solar cell formed by depositing the Ti3C2T MXene on n-Si, where Ti3C2T serves as both the electrode for hole collection and the component to form the Schottky junction with n-Si [74], as demonstrated in Fig. 10a. Figure 10b shows the illuminated J–V curves for the devices prepared by depositing MXene using floating and oven transfer methods, respectively, with the initial efficiencies of 0.58% and 4.20%. Moreover, as exhibited in Fig. 10c, the PCE of the as-prepared device by oven transfer can be further improved, i.e., > 9% by a two-step chemical treatment using HCl and AuCl3 in sequence and > 10% by further introducing a PDMS antireflection layer. More investigations indicate that the SiO2 thin layer formed between Ti3C2T and n-Si during oven transfer plays the key role to suppress carrier recombinations and thus to achieve the higher device performance as compared to the floating method. For the improved device performance by the two-step chemical treatment, it can be attributed to the increased conductivity for the MXene layer due to the doping effect introduced by HCl, the increased Schottky barrier height (note: The WF of the MXene layer increases from 4.80 to 4.84 and further to 4.93 eV for the pristine, HCl- and AuCl3-treated samples) and enhanced charge transfer because of the formed Au nanoparticles from AuCl3.

Conclusion and Prospect

In this review, all applications and developments of the Ti3C2T MXene in solar cells since the first report in 2018 are detailedly summarized. As can be seen, the Ti3C2T MXene mainly plays three roles, i.e., additive, electrode and charge (electron or hole) transport layer, and the type of the applied solar cells includes perovskite (mainly), organic (mainly), silicon wafer-based and quantum dot-sensitized solar cells. (Note: The functions in different roles for MXenes applied in solar cells are briefly summarized in Table 1, and meanwhile, the key device parameters are compiled in Tables 2, 3 and 4, according to the roles played by the Ti3C2T MXene.) Moreover, there is one report regarding a hybrid device combining electricity generation and storage, i.e., the so-called PV supercapacitor in which all electrodes are Ti3C2T, and the organic PV device and supercapacitor share one common electrode [72].

Table 1

Summary of the functions/properties of MXenes in different roles played in solar cells

Additive	Accelerating the electron transfer, like an “electron” bridge Improving crystallinity of the perovskite materials Tuning the work function of the carrier transport materials and other properties such as conductivity Passivating the surface and engineering interface
Electrode	Metallic conductivity, high transparency, outstanding flexibility and adjustable work functions To form hybrid electrodes with other conducting nanomaterials, such as carbon nanotubes or metallic nanowires
HTL/ETL	Easily tunable work functions and carrier conducting properties

Table 2

Summary of the key parameters for the solar cells employing MXenes as an additive

Device structure	Jsc (mA cm−2)	Voc (V)	FF (%)	PCE (%)	Year	References
ITO/SnO2/MAPbI3:Ti3C2Tx/Spiro-OMeTAD/Au	22.26	1.03	76.00	17.41	2018	[51]
FTO/c-TiO2/m-TiO2/CsFAMA-TQD/Spiro-OMeTAD:Cu1.8S/Au	24.12	1.14	78.70	21.64	2020	[60]
ITO/SnO2-Ti3C2/MAPbI3/Spiro-OMeTAD/Ag	23.14	1.06	75.00	18.34	2019	[61]
FTO/TiO2:SnO2:Ti3C2Tx/(FAPbI3)0.97 (MAPbBr3)0.03/Spiro-OMeTAD/Au	22.03	1.10	77.78	18.90	2020	[62]
FTO/c-TiO2:Ti3C2Tx/m-TiO2:Ti3C2Tx/Ti3C2Tx/MAPbI3:Ti3C2Tx/Spiro-OMeTAD/Au	23.82	1.09	77.60	20.14	2019	[58]
ITO/PEDOT:PSS:Ti3C2Tx/PBDB-T:ITIC/PFN-Br/Al	17.08	0.91	70.93	11.02	2020	[64]
ITO/PEDOT:PSS:Ti3C2Tx/PM6:Y6/PFN-Br/Al	25.63	0.83	68.40	14.55	2020	[64]
ITO/ZnO:Ti3C2Tx/PBDB-T:ITIC/MoO3/Ag	18.63	0.93	70.39	12.20	2020	[65]
ITO/ZnO:Ti3C2Tx/PM6:Y6/MoO3/Ag	26.38	0.83	75.40	16.51	2020	[65]
ITO/ZnO:Ti3C2Tx/PTB7:PC71BM /MoO3/Ag	17.53	0.77	69.33	9.36	2020	[65]

Table 3

Summary of the key parameters for the solar cells employing MXenes as electrodes

Device structure	Jsc (mA cm−2)	Voc (V)	FF (%)	PCE (%)	Year	References
FTO/TiO2/MAPbI3/Ti3C2Tx	22.96	0.95	63.00	13.83	2019	[52]
FTO/c-TiO2/CPbBr3/Carbon:CNT:Ti3C2Tx	7.16	1.357	72.97	7.09	2019	[70]
Al/PrC60MA/PTB7-Th: PC71BM/PEDOT:PSS/MXene-AgNW-PUA	14.62	0.79	61.00	7.16	2019	[71]
Al/PDINO/PC71BM/PBDB-T: ITIC/PEDOT:PSS/MXene-AgNW-PUA	13.98	0.86	64.00	7.70	2019	[71]
Al/PDINO/PBDB-T:ITIC:PC71BM/PEDOT:PSS/MXene-AgNW-PUA	14.85	0.88	63.00	8.30	2019	[71]
Glass/Ti3C2Tx/PEDOT:PSS/PM6:Y6/PFN-Br/Al	24.97	0.84	64.90	13.62	2020	[72]
Ti3C2Tx/n+-Si/n-Si/p+-Si/Al2O3/SiNx/Ag/Al	36.70	0.54	57.99	11.47	2019	[73]
PDMS/Au/Ti3C2Tx/SiO2/n-Si/In:Ga	27.21	0.574	65.00	10.22	2019	[74]

Table 4

Summary of the key parameters for the solar cells employing MXenes as hole/electron transport layers

Device structure	Jsc (mA·cm−2)	Voc (V)	FF (%)	PCE (%)	Year	References
FTO/TiO2/CsPbBr3/Ti3C2Tx/Carbon (HTL)	8.54	1.444	73.08	9.01	2019	[77]
ITO/U-Ti3C2Tx/PBDB-T:ITIC/Ca/Al (HTL)	15.98	0.89	64.00	9.02	2019	[53]
ITO/Ti3C2Tx/PBDB-T:ITIC/PFN-Br/Al (HTL)	17.85	0.88	67.06	10.53	2019	[80]
PDMS/Au/Ti3C2Tx/SiO2/n-Si/In:Ga (HTL)	27.21	0.574	65.00	10.22	2019	[74]
ITO/Ti3C2Tx/CH3NH3PbI3/Spiro-OMeTAD/Ag (ETL)	22.63	1.08	70.00	17.17	2019	[78]
FTO/MXene/SnO2/perovskite/Spiro-OMeTAD/Au (ETL)	24.34	1.11	76.40	20.65	2020	[79]
ITO/UH-Ti3C2Tx/PBDB-T:ITIC/MoO3/Al (ETL)	17.36	0.87	60.00	9.06	2019	[53]

Generally speaking, report of MXenes in application of solar cells just began since the last quarter of 2018, and the related study is still in its infant stage mainly focusing on exploration of the feasibility in varying solar cells. Device performance including PCE and stability still has plenty of room for improvement [81]. Moreover, the influence of different contaminants on Ti3C2T and device performance is still lacking. Here, it should also be noted that the previous reports are mainly based on experiments. Accordingly, prediction and optimization of the material properties of MXenes terminated with different functional groups based on theoretical/simulation approaches are necessary for more accurately guiding the experiments [63, 82–84].

On the other hand, the properties of MXenes including morphology, conductivity, transparency, terminating groups, WF and stability are sensitive to the fabrication process. In the meantime, considering the application scenarios, i.e., solar cells, developing the fabrication methods of MXenes with accurately controllable properties, large scale and low cost is necessary [85-87]. Moreover, besides applications in solar cells, other optoelectronic devices such as light-emitting diodes and photodetectors can find more innovations because of the unique optical, electrical and mechanical properties of MXenes. Another issue needing to be concerned is the stability of MXenes if they were exposed to air for a long time due to oxidation, which would increase their resistance and thus reduce the device performance. Thus, appropriate passivation and/or encapsulation is necessary for stable working of the related devices [88-91]. In addition, F-free synthesis of the Ti3C2T MXene with high purity has attracted significant attention because of the high safety and environmental friendliness.

There exist more than 100 stoichiometric MXene compositions and a limitless number of solid solutions, which would provide not only unique combinations of properties but also plenty of ways to tune them by changing the ratios of M or X elements [92]. To date, only the first discovered MXene, Ti3C2T, has been applied in the PV field, while other types of MXenes have rarely been reported in application of solar cells. The large underexplored family of MXenes with unique properties make us believe that many exciting discoveries are to come. We optimistically expect that MXenes-based PV devices could achieve a great progress in the near future with further efforts by the researchers in this area.

Based on the above discussion and analysis, several suggestions are given for pushing exploration of MXene’s applications in solar cells: (1) deep understanding into the adjustment and optimization of the Fermi level and the electrical properties for Ti3C2T MXene materials terminated with varying functional groups based on theoretical prediction and experimental examination for better guiding experimental realization of high-performance solar cells; (2) further improvement of device performance such as PCE and stability based on (1), optimization of each interface in solar cells and incorporation of additional light management structures/components; (3) development of the related flexible PV devices considering the good flexibility of the MXene materials; (4) exploration of novel multifunctional integrated devices such as PV supercapacitors/secondary batteries and self-powered sensors considering the advantages of high transparency, abundant electrochemical active sites and remarkable adjustment of the electrical properties by functional groups for MXenes; and (5) in-depth study of the mechanism of the degraded performance for MXenes in air, exploration of the appropriate passivation and/or encapsulation measures and development of fabrication approaches suitable for solar cell applications. Moreover, besides the further development of the Ti3C2T MXene, exploring other suitable MXenes applicable in solar cells is necessary to enrich the related studies and thus to find more opportunities to realize PV devices and/or integrated devices with high performance-to-cost ratios.