Literature DB >> 34096283

Exact Analytical Solution of the Ground-State Hydrogenic Problem with Soft Coulomb Potential.

Chen Li1.   

Abstract

We provide the exact analytical solution of the ground-state hydrogenic problem with soft Coulomb potential in 1-, 2- and 3-D. We show that the wave function is an analytical function of the inverse of the soft Coulomb potential and identify a power term, an exponentially decaying term and a mildly varying modulator function on the exponential. In approaching the bare Coulomb limit, only the exponentially decaying term survives in 2D and 3D and converges to the well-known result. This is in contrast with the 1D case, where the wave function shrinks to a delta function with a total energy of minus infinity. The asymptotic behavior of the energy in such limit has been analyzed. Moreover, by analyzing the solution in different dimensions, we find that the total energy increases with dimension and scales linearly rather than quadratically with the nuclear charge Z in the large Z limit.

Entities:  

Year:  2021        PMID: 34096283     DOI: 10.1021/acs.jpca.1c00698

Source DB:  PubMed          Journal:  J Phys Chem A        ISSN: 1089-5639            Impact factor:   2.781


  1 in total

1.  Exact Analytical Form of Diatomic Molecular Orbitals.

Authors:  Yunzhi Li; Chen Li
Journal:  ACS Omega       Date:  2022-06-19
  1 in total

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