Literature DB >> 34076424

C-H Amination via Electrophotocatalytic Ritter-type Reaction.

Tao Shen1, Tristan H Lambert1.   

Abstract

A method for C-H bond amination via an electrophotocatalytic Ritter-type reaction is described. The reaction is catalyzed by a trisaminocyclopropenium (TAC) ion in an electrochemical cell under irradiation. These conditions convert benzylic C-H bonds to acetamides without the use of a stoichiometric chemical oxidant. A range of functionality is shown to be compatible with this transformation, and several complex substrates are demonstrated.

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Year:  2021        PMID： 34076424      PMCID： PMC8935655          DOI： 10.1021/jacs.1c03718

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   16.383


  55 in total

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7.  Electrophotocatalytic C-H Functionalization of Ethers with High Regioselectivity.

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  6 in total

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  6 in total

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