Adsorption performance of modified agricultural waste materials for removal of emerging micro-contaminant bisphenol A: A comprehensive review.

This review is an attempt to assess the adsorption performance of different green adsorbents derived from agricultural waste materials (AWMs) that were used for the elimination of bisphenol A (BPA) from aqueous matrices. Different processes including grafting, polymerization, activation and chemical treatment have been applied to functionalize and modify agricultural waste materials for the purposes of increasing their adsorptive performances toward BPA. The highest reported adsorption capacity of adsorbent from agricultural waste for the uptake of BPA is the highly microporous carbon adsorbent derived from Argan nut shell (1408 mg g-1). Hydrogen bonding, hydrophobic and π-π interactions were reported in most studies as the main mechanisms governing the adsorption of BPA onto agricultural waste adsorbents. Equilibrium isotherm and kinetic studies for the uptake of BPA onto agricultural waste adsorbents were best described by Langmuir/Freundlich model and pseudo-second order model, respectively. Despite the effective elimination of BPA by various agricultural waste adsorbents, an appropriate selection of elution solvent is important for effective desorption of BPA from spent adsorbent. To date, ethanol, diethyl ether-methanol, methanol-acetic acid, mineral acids and sodium hydroxide are the most eluents applied for desorption of BPA molecules loaded onto AW-adsorbents. Looking toward the future, studies on the agricultural waste adsorbents based on polymers, activated carbons, nanoparticles and highly microporous carbons should be mostly considered by the researchers toward removing BPA. These future studies should be performed both in laboratory, pilot and industrial scales, and also should report the sustainable techniques for disposal of the spent AW-adsorbents after lose their adsorption performance on BPA.