Evolution of Earth-Abundant 3 d-Metallaelectro-Catalyzed C-H Activation: From Chelation-Assistance to C-H Functionalization without Directing Groups.

Catalyzed C-H functionalizations have emerged as a transformative platform for molecular syntheses. Despite of indisputable advances, oxidative C-H activations have been largely restricted to precious transition metals and stoichiometric amounts of chemical oxidants. In contrast, we herein discuss the potential of earth-abundant, environmentally-benign 3d transition metals for C-H activation, which has recently gained major momentum. Thus, a strategy for full resource economy has been established in our group, with green electricity as a renewable redox agent, giving valuable hydrogen as the sole byproduct under redox mediator-free conditions. In this account, we detail our accomplishments in 3d metallaelectrocatalysis towards green syntheses until March 2021.