Literature DB >> 34023863

Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field.

Tsuneomi Kawasaki1, Yoshiyasu Kaimori1, Seiya Shimada1, Natsuki Hara1, Susumu Sato1, Kenta Suzuki1, Toru Asahi2, Arimasa Matsumoto1, Kenso Soai3.   

Abstract

Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess, i.e., the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered by an electric field.

Entities:  

Year:  2021        PMID: 34023863     DOI: 10.1039/d1cc02162a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Single-crystal structure analysis of non-deuterated triglycine sulfate by neutron diffraction at 20 and 298 K: a new disorder model for the 298 K structure.

Authors:  Yukana Terasawa; Takashi Ohhara; Sota Sato; Satoshi Yoshida; Toru Asahi
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2022-02-08
  1 in total

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