Literature DB >> 34002179

Small rings in the bigger picture: ring expansion of three- and four-membered rings to access larger all-carbon cyclic systems.

Bohdan Biletskyi1, Pierre Colonna1, Kévin Masson1, Jean-Luc Parrain1, Laurent Commeiras1, Gaëlle Chouraqui1.   

Abstract

The release of the inherent ring strain of cyclobutane and cyclopropane derivatives allows a rapid build-up of molecular complexity. This review highlights the state-of-the-art of the ring expansions of three- and four-membered cycles and is organised by types of reactions with emphasis on the reaction mechanisms. Selected examples are discussed to illustrate the synthetic potential of this elegant synthetic tool.

Entities:  

Year:  2021        PMID: 34002179     DOI: 10.1039/d0cs01396j

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN: 0306-0012            Impact factor:   54.564


  4 in total

1.  Palladium-Catalyzed Access to Benzocyclobutenone-Derived Ketonitrones via C(sp2)-H Functionalization.

Authors:  Jakub Brześkiewicz; Rafał Loska
Journal:  Org Lett       Date:  2022-05-25       Impact factor: 6.072

2.  Asymmetric β-arylation of cyclopropanols enabled by photoredox and nickel dual catalysis.

Authors:  Jianhua Wang; Xiaoxun Li
Journal:  Chem Sci       Date:  2022-02-17       Impact factor: 9.825

3.  Palladium-catalyzed selective C-C bond cleavage and stereoselective alkenylation between cyclopropanol and 1,3-diyne: one-step synthesis of diverse conjugated enynes.

Authors:  Bedadyuti Vedvyas Pati; Asit Ghosh; Komal Yadav; Shyam Kumar Banjare; Shalini Pandey; Upakarasamy Lourderaj; Ponneri C Ravikumar
Journal:  Chem Sci       Date:  2022-02-08       Impact factor: 9.825

4.  An efficient approach to angular tricyclic molecular architecture via Nazarov-like cyclization and double ring-expansion cascade.

Authors:  Yun-Peng Wang; Kun Fang; Yong-Qiang Tu; Jun-Jie Yin; Qi Zhao; Tian Ke
Journal:  Nat Commun       Date:  2022-04-28       Impact factor: 17.694

  4 in total

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