Literature DB >> 33989372

Titanocene pnictinidene complexes.

Malte Fischer1, Fabian Reiß1, Christian Hering-Junghans1.   

Abstract

The phospha-Wittig reagent MesTerPPMe3 (MesTer = 2,6-{2,4,6-Me3-C6H2}-C6H3) and arsa-Wittig reagent DipTerAsPMe3 (DipTer = 2,6-{2,6-iPr2-C6H3}-C6H3) have been employed to synthesize the titanocene complexes Cp2Ti(PMe3)PnAr (Pn = P, As) with terminal phosphinidene or arsinidene ligands, respectively. Ab initio studies show that the description as singlet biradicaloids in their ground state is warranted.

Entities:  

Year:  2021        PMID: 33989372     DOI: 10.1039/d1cc01305j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

1.  Structural Snapshots in Reversible Phosphinidene Transfer: Synthetic, Structural, and Reaction Chemistry of a Sn═P Double Bond.

Authors:  Malte Fischer; Matthew M D Roy; Lewis L Wales; Mathias A Ellwanger; Andreas Heilmann; Simon Aldridge
Journal:  J Am Chem Soc       Date:  2022-05-10       Impact factor: 16.383

2.  1-Zirconacyclobuta-2,3-dienes: synthesis of organometallic analogs of elusive 1,2-cyclobutadiene, unprecedented intramolecular C-H activation, and reactivity studies.

Authors:  Xinzhe Shi; Sihan Li; Melanie Reiß; Anke Spannenberg; Thorsten Holtrichter-Rößmann; Fabian Reiß; Torsten Beweries
Journal:  Chem Sci       Date:  2021-11-23       Impact factor: 9.825

Review 3.  Latest News: Reactions of Group 4 Bis(trimethylsilyl)acetylene Metallocene Complexes and Applications of the Obtained Products.

Authors:  Uwe Rosenthal
Journal:  ChemistryOpen       Date:  2021-12       Impact factor: 2.630

4.  Metal-Free N-H Bond Activation by Phospha-Wittig Reagents.

Authors:  Fabian Dankert; Jan-Erik Siewert; Priyanka Gupta; Florian Weigend; Christian Hering-Junghans
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-04       Impact factor: 16.823

  4 in total

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