Literature DB >> 33942839

Bicyclic (alkyl)(amino)carbene stabilized zinc(0) complex with singlet biradicaloid ground state.

N M Rajendran1, Nimisha Gautam1, Pallavi Sarkar2, Jasimuddin Ahmed1, Arpan Das1, Shubhajit Das2, Swapan K Pati2, Swadhin K Mandal1.   

Abstract

A storable bicyclic (alkyl)(amino)carbene (BICAAC) stabilized two coordinate zinc(0) complex [(BICAAC)2Zn] (2) was synthesized. DFT calculations reveal that BICAAC plays a decisive role in imparting the stability to 2. This complex activates the C(sp3)-Cl bond of trityl chloride generating the Gomberg's free radical with greater efficiency than metallic Zn powder.

Entities:  

Year:  2021        PMID： 33942839     DOI： 10.1039/d1cc01298c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Catalytic Decomposition of Long-Chain Olefins to Propylene via Isomerization-Metathesis Using Latent Bicyclic (Alkyl)(Amino)Carbene-Ruthenium Olefin Metathesis Catalysts.

Authors:  Márton Nagyházi; Ádám Lukács; Gábor Turczel; Jenő Hancsók; József Valyon; Attila Bényei; Sándor Kéki; Róbert Tuba
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-19       Impact factor: 16.823

2.  Ultra-Long Lived Luminescent Triplet Excited States in Cyclic (Alkyl)(amino)carbene Complexes of Zn(II) Halides.

Authors:  Ondřej Mrózek; Markus Gernert; Andrey Belyaev; Mousree Mitra; Lars Janiak; Christel M Marian; Andreas Steffen
Journal:  Chemistry       Date:  2022-06-21       Impact factor: 5.020
  2 in total

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