| Literature DB >> 33936757 |
Shaaban K Mohamed1,2, Awad I Said3, Joel T Mague4, Talaat I El-Emary3, Mehmet Akkurt5, Sahar M I Elgarhy6.
Abstract
In the title compound, C33H26N4O4, the two fused five-membered rings and their N-bound aromatic substituents form a pincer-like motif. The relative conformations about the three chiral carbon atoms are established. In the crystal, a combination of C-H⋯O and C-H⋯N hydrogen bonds and C-H⋯π(ring) inter-actions leads to the formation of layers parallel to the bc plane. A Hirshfeld surface analysis indicates that the most significant contributions to the crystal packing are from H⋯H (44.3%), C⋯H/H⋯C (29.8%) and O⋯H/H⋯O (15.0%) contacts. © Mohamed et al. 2021.Entities:
Keywords: C—H⋯π(ring); Hirshfeld surface analysis; crystal structure; hydrogen bond; oxazole; pyrrole
Year: 2021 PMID: 33936757 PMCID: PMC8025861 DOI: 10.1107/S2056989021002358
Source DB: PubMed Journal: Acta Crystallogr E Crystallogr Commun