Literature DB >> 33929231

Disorder-Enhanced and Disorder-Independent Transport with Long-Range Hopping: Application to Molecular Chains in Optical Cavities.

Nahum C Chávez1,2, Francesco Mattiotti1,3,4, J A Méndez-Bermúdez2, Fausto Borgonovi1,5, G Luca Celardo2.   

Abstract

Overcoming the detrimental effect of disorder at the nanoscale is very hard since disorder induces localization and an exponential suppression of transport efficiency. Here we unveil novel and robust quantum transport regimes achievable in nanosystems by exploiting long-range hopping. We demonstrate that in a 1D disordered nanostructure in the presence of long-range hopping, transport efficiency, after decreasing exponentially with disorder at first, is then enhanced by disorder [disorder-enhanced transport (DET) regime] until, counterintuitively, it reaches a disorder-independent transport (DIT) regime, persisting over several orders of disorder magnitude in realistic systems. To enlighten the relevance of our results, we demonstrate that an ensemble of emitters in a cavity can be described by an effective long-range Hamiltonian. The specific case of a disordered molecular wire placed in an optical cavity is discussed, showing that the DIT and DET regimes can be reached with state-of-the-art experimental setups.

Entities:  

Year:  2021        PMID: 33929231     DOI: 10.1103/PhysRevLett.126.153201

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  2 in total

1.  Vibrational Polaritons in Disordered Molecular Ensembles.

Authors:  Bar Cohn; Shmuel Sufrin; Arghyadeep Basu; Lev Chuntonov
Journal:  J Phys Chem Lett       Date:  2022-08-31       Impact factor: 6.888

2.  Static Disorder has Dynamic Impact on Energy Transport in Biomimetic Light-Harvesting Complexes.

Authors:  Leo M Hamerlynck; Amanda J Bischoff; Julia R Rogers; Trevor D Roberts; Jing Dai; Phillip L Geissler; Matthew B Francis; Naomi S Ginsberg
Journal:  J Phys Chem B       Date:  2022-10-03       Impact factor: 3.466

  2 in total

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