Detection of Adulteration in Infant Formula Based on Ensemble Convolutional Neural Network and Near-Infrared Spectroscopy.

Adulteration in dairy products has received world-wide attention, and at the same time, near infrared (NIR) spectroscopy has proven to be a promising tool for adulteration detection given its advantages of real-time response and non-destructive analysis. Regardless, the accurate and robust NIR model for adulteration detection is hard to achieve in practice. Convolutional neural network (CNN), as a promising deep learning architecture, is difficult to apply to such chemometrics tasks due to the high risk of overfitting, despite the breakthroughs it has made in other fields. In this paper, the ensemble learning method based on CNN estimators was developed to address the overfitting and random initialization problems of CNN and applied to the determination of two infant formula adulterants, namely hydrolyzed leather protein (HLP) and melamine. Moreover, a probabilistic wavelength selection method based on the attention mechanism was proposed for the purpose of finding the best trade-off between the accuracy and the diversity of the sub-models in ensemble learning. The overall results demonstrate that the proposed method yielded superiority regression performance over the comparison methods for both studied data sets, and determination coefficients (R2) of 0.961 and 0.995 were obtained for the HLP and the melamine data sets, respectively.