Literature DB >> 33899860

Nucleophilic iodonium interactions (NIIs) in 2-coordinate iodine(I) and silver(I) complexes.

Jas S Ward1, Antonio Frontera2, Kari Rissanen1.   

Abstract

The generality of nucleophilic iodonium interactions (NIIs) has been demonstrated by preparing a range of silver(i) and iodonium (I+) complexes and studying their 15N NMR chemical shifts, with the first example of a NII-complex involving a 2-coordinate silver(i) complex being confirmed by X-ray crystallography, and its nucleophilicity studied by DFT calculations.

Entities:  

Year:  2021        PMID： 33899860     DOI： 10.1039/d1cc01505b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  "Anti-electrostatic" Halogen Bonding between Ions of Like Charge.

Authors:  Jana M Holthoff; Robert Weiss; Sergiy V Rosokha; Stefan M Huber
Journal:  Chemistry       Date:  2021-10-01       Impact factor: 5.020

2.  Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines.

Authors:  Jas S Ward; Rosa M Gomila; Antonio Frontera; Kari Rissanen
Journal:  RSC Adv       Date:  2022-03-21       Impact factor: 3.361

3.  Are bis(pyridine)iodine(I) complexes applicable for asymmetric halogenation?

Authors:  Daniel von der Heiden; Flóra Boróka Németh; Måns Andreasson; Daniel Sethio; Imre Pápai; Mate Erdelyi
Journal:  Org Biomol Chem       Date:  2021-10-06       Impact factor: 3.876
  3 in total

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