| Literature DB >> 33899319 |
Han-Ying Liu1, Ryan J Schwamm1, Michael S Hill1, Mary F Mahon1, Claire L McMullin1, Nasir A Rajabi1.
Abstract
Copper-alumanyl complexes, [LCu-Al(SiNDipp )], where L=carbene=NHCiPr (N,N'-diisopropyl-4,5-dimethyl-2-ylidene) and Me2 CAAC (1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethyl-pyrrolidin-2-ylidene) and featuring unsupported Al-Cu bonds, have been prepared. Divergent reactivity observed with carbodiimides and CO2 implies an ambiphilicity in the Cu-Al interaction that is dependent on the identity of the carbene co-ligand.Entities:
Keywords: aluminum; coordination modes; copper; ligand effects; metal-metal interactions
Year: 2021 PMID： 33899319 DOI： 10.1002/anie.202104658
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336