Literature DB >> 33889901

Radical trifluoromethylation.

Haiwen Xiao1, Zhenzhen Zhang, Yewen Fang, Lin Zhu, Chaozhong Li.   

Abstract

The trifluoromethyl group plays an increasingly important role in pharmaceuticals, agrochemicals and materials. This tutorial describes recent advances in trifluoromethylation of carbon-centered radical intermediates.

Entities:  

Year:  2021        PMID： 33889901     DOI： 10.1039/d1cs00200g

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN： 0306-0012            Impact factor:   54.564


  9 in total

1.  Radical 1,2,3-tricarbofunctionalization of α-vinyl-β-ketoesters enabled by a carbon shift from an all-carbon quaternary center.

Authors:  Qi Zhang; Mong-Feng Chiou; Changqing Ye; Xiaobin Yuan; Yajun Li; Hongli Bao
Journal:  Chem Sci       Date:  2022-05-02       Impact factor: 9.969

2.  Electrooxidative tricyclic 6-7-6 fused-system domino assembly to allocolchicines by a removable radical strategy.

Authors:  Yan Zhang; Chanchan Ma; Zhenzhi Cai; Julia Struwe; Shengjie Chen; Jinming Xu; Shiyin Li; Wangyu Zeng; Lutz Ackermann
Journal:  Green Chem       Date:  2022-04-13       Impact factor: 11.034

3.  Photoinduced Trifluoromethylation with CF3Br as a Trifluoromethyl Source: Synthesis of α-CF3-Substituted Ketones.

Authors:  Ransong Ma; Zhoubin Deng; Ke-Hu Wang; Junjiao Wang; Danfeng Huang; Yingpeng Su; Yulai Hu; Xiaobo Lv
Journal:  ACS Omega       Date:  2022-04-12

4.  Dibenzocycloheptanones construction through a removable P-centered radical: synthesis of allocolchicine analogues.

Authors:  Yan Zhang; Zhenzhi Cai; Julia Struwe; Chanchan Ma; Wangyu Zeng; Xinyi Liao; Min Xu; Lutz Ackermann
Journal:  Chem Sci       Date:  2021-11-09       Impact factor: 9.825

5.  Photoredox-mediated hydroalkylation and hydroarylation of functionalized olefins for DNA-encoded library synthesis.

Authors:  Shorouk O Badir; Alexander Lipp; Matthias Krumb; María Jesús Cabrera-Afonso; Lisa Marie Kammer; Victoria E Wu; Minxue Huang; Adam Csakai; Lisa A Marcaurelle; Gary A Molander
Journal:  Chem Sci       Date:  2021-08-05       Impact factor: 9.825

6.  Iridium-Catalyzed C-H Borylation of CF3-Substituted Pyridines.

Authors:  Hafiza Tayyaba Shahzadi; Saman Fatima; Naseem Akhter; Meshari Alazmi; Alshammari Nawaf; Kamaleldin B Said; Amer AlGhadhban; Abdel Moneim E Sulieman; Rahman Shah Zaib Saleem; Ghayoor Abbas Chotana
Journal:  ACS Omega       Date:  2022-03-24

7.  New Insights into the Actual H-Abstraction Activities of Important Oxygen and Nitrogen Free Radicals: Thermodynamics and Kinetics in Acetonitrile.

Authors:  Yan-Hua Fu; Guang-Bin Shen; Kai Wang; Xiao-Qing Zhu
Journal:  ACS Omega       Date:  2022-07-12

8.  A Mild and Regioselective Route to Fluoroalkyl Aromatic Compounds via Directed Cycloaddition Reactions.

Authors:  David L Cousins; Yee Hwee Lim; Joseph P A Harrity
Journal:  J Org Chem       Date:  2022-07-08       Impact factor: 4.198

9.  Direct C-H Trifluoromethylation of (Hetero)Arenes in Water Enabled by Organic Photoredox-Active Amphiphilic Nanoparticles.

Authors:  Fabian Eisenreich; Anja R A Palmans
Journal:  Chemistry       Date:  2022-07-28       Impact factor: 5.020
  9 in total

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