All-Inorganic Lead Free Double Perovskite Li-Battery Anode Material Hosting High Li+ Ion Concentrations.

Perovskite materials, as a multifunctional material, have been widely applied in the field of electrochemistry due to its ion migration properties. Although the lead based halide perovskite has been applied in the anode of the lithium battery, it is necessary to develop new lead-free perovskite anode materials because of its the instability and environmental unfriendliness. Herein, we develop a facile grinding method to prepare ultrahigh Li+ concentration doping Cs2NaBiCl6 powders, which are used as the anode material of the lithium battery. The assembled battery possesses a stable specific capacity of about 300 mA h g-1 with over 99% Coulombic efficiency. Owing to their particular crystal structure with high adjustability, the double perovskite materials have promising potentials in lithium storage applications.