Heavy-atom-modified chalcogen-fused triarylamine organic materials are becoming increasingly important in the photochemical sciences. In this context, the general and direct dehydrogenative C-H phenochalcogenazination of phenols with the heavier chalcogens selenium and tellurium is herein described. The latter dehydrogenative C-N bond-forming processes operate under simple reaction conditions with highly sustainable O2 serving as the terminal oxidant.
Heavy-atom-modified chalcogen-fun class="Chemical">sed triarylamine organic materials are becoming increasingly important in the photochemical sciences. In this context, the general and direct dehydrogenative C-H phenochalcogenazination of phenols with the heavier chalcogens selenium and tellurium is herein described. The latter dehydrogenative C-N bond-forming processes operate under simple reaction conditions with highly sustainable O2serving as the terminal oxidant.
Authors: Daniel A Corbin; Christopher Cremer; Katherine O Puffer; Brian S Newell; Frederic W Patureau; Garret M Miyake Journal: ChemCatChem Date: 2022-07-08 Impact factor: 5.497