Carbon materials for extraction of uranium from seawater.

With the rapid growth of population and industrialization, the energy crisis and environmental pollution as two main difficulties urgently need to be solved nowadays. The development and utilization of nuclear energy is of great significance for solving energy support, national security and environmental protection. As the raw material of nuclear energy, a lot of uranium in seawater provide a guarantee for the sustainable and green development of nuclear power plants. Recently, various new carbon-based materials (e.g., carbon nanofibers, multiwalled carbon nanotube, graphene) have been attracted widely intense interest in extraction of uranium from seawater due to large specific surface area, excellent acid-base resistance, high adsorption performance, environmental friendly and low cost. Thus, the systematic reviews concerning the extraction of uranium from seawater on various carbon-based materials were highly desirable. In this review, the extraction methods of uranium from seawater, including electrochemical, photocatalytic and adsorption methods are briefly introduced. Then the application and mechanism of four generation carbon-based materials on the extraction of uranium from seawater are systematically reviewed in details. Finally, the current challenges and future trends of uranium extraction from seawaters are proposed. This review provides the guideline for designing carbon-based materials with high adsorption capacity and exceptional selectivity for U(VI) extraction from seawater.