Literature DB >> 33803395

Effect of Iodine Filler on Photoisomerization Kinetics of Photo-Switchable Thin Films Based on PEO-BDK-MR.

Qais M Al-Bataineh1, A A Ahmad1, A M Alsaad1, I A Qattan2, Ihsan A Aljarrah1, Ahmad D Telfah3,4.   

Abstract

We report the effect of an iodine filler on photoisomerization kinetics of photo-switchable PEO-BDK-MR thin films. The kinetics of photoisomerization and time progression of PEO-BDK-MR/I2 nanocomposite thin films are investigated using UV-Vis, FTIR spectroscopies, and modified mathematical models developed using new analytical methods. Incorporating iodine filler into the PEO-BDK-MR polymeric matrix enhances the isomerization energy barrier and considerably increases the processing time. Our outcomes propose that enhanced photoisomerized and time processed (PEO-BDK-MR)/I2 thin films could be potential candidates for a variety of applications involving molecular solar thermal energy storage media.

Entities:  

Keywords:  Benzyl Dimethyl Ketal (BDK); Iodine (I2); Methyl-Red (MR); Polyethylene Oxide (PEO); complex composite thin films; molecular solar thermal energy storage media; photoisomerization processes

Year:  2021        PMID: 33803395      PMCID: PMC7967190          DOI: 10.3390/polym13050841

Source DB:  PubMed          Journal:  Polymers (Basel)        ISSN: 2073-4360            Impact factor:   4.329


  35 in total

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Journal:  J Am Chem Soc       Date:  2004-03-17       Impact factor: 15.419

2.  Attraction or Repulsion? London Dispersion Forces Control Azobenzene Switches.

Authors:  Luca Schweighauser; Marcel A Strauss; Silvia Bellotto; Hermann A Wegner
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3.  Oligoazobenzenes--switching in a new dimension.

Authors:  Raphael Reuter; Nik Hostettler; Markus Neuburger; Hermann A Wegner
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4.  Photoswitchable Antimetabolite for Targeted Photoactivated Chemotherapy.

Authors:  Carlo Matera; Alexandre M J Gomila; Núria Camarero; Michela Libergoli; Concepció Soler; Pau Gorostiza
Journal:  J Am Chem Soc       Date:  2018-10-22       Impact factor: 15.419

5.  Intermolecular London Dispersion Interactions of Azobenzene Switches for Tuning Molecular Solar Thermal Energy Storage Systems.

Authors:  Anne Kunz; Andreas H Heindl; Ambra Dreos; Zhihang Wang; Kasper Moth-Poulsen; Jonathan Becker; Hermann A Wegner
Journal:  Chempluschem       Date:  2019-08-12       Impact factor: 2.863

6.  Effects of Trehalose on Thermodynamic Properties of Alpha-synuclein Revealed through Synchrotron Radiation Circular Dichroism.

Authors:  Paolo Ruzza; Rohanah Hussain; Barbara Biondi; Andrea Calderan; Isabella Tessari; Luigi Bubacco; Giuliano Siligardi
Journal:  Biomolecules       Date:  2015-05-04

7.  A High Energy Density Azobenzene/Graphene Oxide Hybrid with Weak Nonbonding Interactions for Solar Thermal Storage.

Authors:  Wenhui Pang; Jijun Xue; Hua Pang
Journal:  Sci Rep       Date:  2019-03-26       Impact factor: 4.379

8.  Covalent functionalization of graphene by azobenzene with molecular hydrogen bonds for long-term solar thermal storage.

Authors:  Yiyu Feng; Hongpo Liu; Wen Luo; Enzuo Liu; Naiqin Zhao; Katsumi Yoshino; Wei Feng
Journal:  Sci Rep       Date:  2013-11-19       Impact factor: 4.379

9.  Molecular solar thermal energy storage in photoswitch oligomers increases energy densities and storage times.

Authors:  Mads Mansø; Anne Ugleholdt Petersen; Zhihang Wang; Paul Erhart; Mogens Brøndsted Nielsen; Kasper Moth-Poulsen
Journal:  Nat Commun       Date:  2018-05-16       Impact factor: 14.919

10.  Solar Energy Storage by Molecular Norbornadiene-Quadricyclane Photoswitches: Polymer Film Devices.

Authors:  Anne Ugleholdt Petersen; Anna I Hofmann; Méritxell Fillols; Mads Mansø; Martyn Jevric; Zhihang Wang; Christopher J Sumby; Christian Müller; Kasper Moth-Poulsen
Journal:  Adv Sci (Weinh)       Date:  2019-04-25       Impact factor: 16.806

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