Literature DB >> 33798352

Synthesis of Yttrium Superhydride Superconductor with a Transition Temperature up to 262 K by Catalytic Hydrogenation at High Pressures.

Elliot Snider1, Nathan Dasenbrock-Gammon2, Raymond McBride1, Xiaoyu Wang3, Noah Meyers1, Keith V Lawler4, Eva Zurek3, Ashkan Salamat5, Ranga P Dias1,2.   

Abstract

The recent observation of room-temperature superconductivity will undoubtedly lead to a surge in the discovery of new, dense, hydrogen-rich materials. The rare earth metal superhydrides are predicted to have very high-T_{c} superconductivity that is tunable with changes in stoichiometry or doping. Here we report the synthesis of an yttrium superhydride that exhibits superconductivity at a critical temperature of 262 K at 182±8  GPa. A palladium thin film assists the synthesis by protecting the sputtered yttrium from oxidation and promoting subsequent hydrogenation. Phonon-mediated superconductivity is established by the observation of zero resistance, an isotope effect and the reduction of T_{c} under an external magnetic field. The upper critical magnetic field is 103 T at zero temperature.

Entities:  

Year:  2021        PMID: 33798352     DOI: 10.1103/PhysRevLett.126.117003

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  5 in total

1.  Combining pressure and electrochemistry to synthesize superhydrides.

Authors:  Pin-Wen Guan; Russell J Hemley; Venkatasubramanian Viswanathan
Journal:  Proc Natl Acad Sci U S A       Date:  2021-11-16       Impact factor: 11.205

2.  Superconductivity above 200 K discovered in superhydrides of calcium.

Authors:  Zhiwen Li; Xin He; Changling Zhang; Xiancheng Wang; Sijia Zhang; Yating Jia; Shaomin Feng; Ke Lu; Jianfa Zhao; Jun Zhang; Baosen Min; Youwen Long; Richeng Yu; Luhong Wang; Meiyan Ye; Zhanshuo Zhang; Vitali Prakapenka; Stella Chariton; Paul A Ginsberg; Jay Bass; Shuhua Yuan; Haozhe Liu; Changqing Jin
Journal:  Nat Commun       Date:  2022-05-23       Impact factor: 17.694

Review 3.  Materials by design at high pressures.

Authors:  Meiling Xu; Yinwei Li; Yanming Ma
Journal:  Chem Sci       Date:  2021-12-09       Impact factor: 9.825

4.  Synthesis, Structure, and Electric Conductivity of Higher Hydrides of Ytterbium at High Pressure.

Authors:  Tomasz Jaroń; Jianjun Ying; Marek Tkacz; Adam Grzelak; Vitali B Prakapenka; Viktor V Struzhkin; Wojciech Grochala
Journal:  Inorg Chem       Date:  2022-05-31       Impact factor: 5.436

5.  Giant enhancement of superconducting critical temperature in substitutional alloy (La,Ce)H9.

Authors:  Jingkai Bi; Yuki Nakamoto; Peiyu Zhang; Katsuya Shimizu; Bo Zou; Hanyu Liu; Mi Zhou; Guangtao Liu; Hongbo Wang; Yanming Ma
Journal:  Nat Commun       Date:  2022-10-10       Impact factor: 17.694

  5 in total

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