Atmospheric Deposition: An Important Determinant of Nutrients and Heavy Metal Levels in Urban Surface Runoff Reaching to the Ganga River.

Excessive loading of water bodies with surface runoff-driven nutrients and heavy metals has become a serious concern worldwide. We investigated the surface runoff quality for nutrients and heavy metals being flushed to the Ganga River, as influenced by atmospheric deposition (AD). We selected three city sites in India, Haridwar, Varanasi, and Howrah, which differ widely with respect to population density and anthropogenic activities. We found distinct spatio-temporal trends in AD input of nutrients and heavy metal with values being highest in Varanasi region followed by Howrah and Haridwar. The runoff nutrients and metals showed strong synchrony with their respective levels in AD input. The concentrations were higher in the first flush. We found strong correlations (R2 = 0.83-0.93; p < 0.001) between AD metals and nutrients with their respective concentration in runoff. For all the studied metals, except Cd, the major proportions were in particulate form. The Cd was present in almost equal proportions in particulate and dissolved fractions. Metals in runoff were found in order as: Zn > Pb > Cu > Ni > Cr > Cd. In general, the concentrations of metals were higher than those reported in other studies. The contamination factor and geo-accumulation index show that the Cd was a major pollutant in the runoff. The pollution load index (PLI) indicates that all three sites are highly polluted. Our study indicates that there is a need to reduce particulate loads. Furthermore, because of the high concentrations of pollutants in the first flush, strategies may be developed to enhance the efficiency of treatment of the first flush of runoff.