Henghan Dai1, Lumin Wang1, Yue Zhao1, Jialu Xue1, Ruicong Zhou1, Chenyang Yu1, Jianing An2, Jinyuan Zhou3, Qiang Chen4, Gengzhi Sun1,5, Wei Huang1,5. 1. Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing 211816, China. 2. Institute of Photonics Technology, Jinan University, Guangzhou 510632, China. 3. School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China. 4. School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, China. 5. Institute of Flexible Electronics (IFE), Northwestern Polytechnical University (NPU), Xi'an 710072, China.
Abstract
Lithium-sulfur (Li-S) batteries as power supply systems possessing a theoretical energy density of as high as 2600 Wh kg-1 are considered promising alternatives toward the currently used lithium-ion batteries (LIBs). However, the insulation characteristic and huge volume change of sulfur, the generation of dissolvable lithium polysulfides (LiPSs) during charge/discharge, and the uncontrollable dendrite formation of Li metal anodes render Li-S batteries serious cycling issues with rapid capacity decay. To address these challenges, extensive efforts are devoted to designing cathode/anode hosts and/or modifying separators by incorporating functional materials with the features of improved conductivity, lithiophilic, physical/chemical capture ability toward LiPSs, and/or efficient catalytic conversion of LiPSs. Among all candidates, molybdenum-based (Mo-based) materials are highly preferred for their tunable crystal structure, adjustable composition, variable valence of Mo centers, and strong interactions with soluble LiPSs. Herein, the latest advances in design and application of Mo-based materials for Li-S batteries are comprehensively reviewed, covering molybdenum oxides, molybdenum dichalcogenides, molybdenum nitrides, molybdenum carbides, molybdenum phosphides, and molybdenum metal. In the end, the existing challenges in this research field are elaborately discussed.
Lithium-sulfur (n>an class="Chemical">Li-S) batteries as power supply systems possessing a theoretical energy density of as high as 2600 Wh kg-1 are considered promising alternatives toward the currently used lithium-ion batteries (LIBs). However, the insulation characteristic and huge volume change of sulfur, the generation of dissolvable lithium polysulfides (LiPSs) duringcharge/discharge, and the uncontrollable dendrite formation of Li metal anodes render Li-S batteries serious cycling issues with rapid capacity decay. To address these challenges, extensive efforts are devoted to designing cathode/anode hosts and/or modifying separators by incorporating functional materials with the features of improved conductivity, lithiophilic, physical/chemical capture ability toward LiPSs, and/or efficient catalytic conversion of LiPSs. Among all candidates, molybdenum-based (Mo-based) materials are highly preferred for their tunable crystal structure, adjustable composition, variable valence of Mo centers, and strong interactions with soluble LiPSs. Herein, the latest advances in design and application of Mo-based materials for Li-S batteries are comprehensively reviewed, coveringmolybdenum oxides, molybdenum dichalcogenides, molybdenum nitrides, molybdenum carbides, molybdenum phosphides, and molybdenum metal. In the end, the existing challenges in this research field are elaborately discussed.