Treatment of real wastewater by photoelectrochemical methods: An overview.

An inadequate and inefficient performance ability of conventional methods to remove persistent organic pollutants urges the need of alternative or complementary advanced wastewater treatments methods to ensure the safer reuse of reclaimed water. Photoelectrochemical methods are emerging as promising options among other advanced oxidation processes because of the higher treatment efficiency achieved due to the synergistic effects of combined photochemical and electrolysis reactions. Synergistic effects of integrated photochemical, electrochemical and photoelectrochemical processes not only increase the hydroxyl radical production; an enhancement on the mineralization ability through various side reactions is also achieved. In this review, fundamental reaction mechanisms of different photoelectrochemical methods including photoelectrocatalysis, photo/solar electro-Fenton, photo anodic oxidation, photoelectroperoxone and photocatalytic fuel cell are discussed. Various integrated photochemical, electrochemical and photoelectrochemical processes and their synergistic effects are elaborated. Different reactor configurations along with the positioning of electrodes, photocatalysts and light source of the individual/combined photoelectrochemical treatment systems are discussed. Modified photoanode and cathode materials used in the photoelectrochemical reactors and their performance ability is presented. Photoelectrochemical treatment of real wastewater such as landfill leachate, oil mill, pharmaceutical, textile, and tannery wastewater are reviewed. Hydrogen production efficiency in the photoelectrochemical process is further elaborated. Cost and energy involved in these processes are briefed, but the applicability of photocatalytic fuel cells to reduce the electrical dependence is also summarised. Finally, the use of photoelectrochemical approaches as an alternative for treating soil washing effluents is currently discussed.