Impact of OA on the Temperature Dependence of PM 2.5 in the Los Angeles Basin.

Air quality policy in the Los Angeles megacity is a guidepost for other megacities. Over the last 2 decades, the policy has substantially reduced aerosol (OA) concentrations and the frequency of high aerosol events in the region. During this time, the emissions contributing to, and the temperature associated with, high aerosol events have changed. Early in the record, aerosol concentrations responded to a variety of different sources. We show that emission control has been effective with a strong decrease in temperature-independent sources. As a result, the response of aerosol to temperature has become a dominant feature of high aerosol events in the basin. The organic fraction of the aerosol (OA) increases with the temperature approaching 35% at 40 °C. We describe a simple conceptual model of aerosol in Los Angeles, illustrating how benzene, toluene, ethylbenzene, and xylenes (BTEX) and isoprene, along with molecules for which these are plausible surrogates such as monoterpenes, are sufficient to explain the observed temperature dependence of PM 2.5.