Shear-induced transitions in colloidal and polymeric liquids.

This review reflects different aspects of wide current studies of the phenomena related to the shear-induced structure transformation in various complex liquids. Experimental data, being the basis of this discussion, were obtained for polymeric liquids (melts, blends, solutions) and different dispersions (colloidal solutions, suspensions, emulsions). The general initial input of shearing is the creation of inhomogeneities which can continue to remain as separate domains, become the nuclei of new phases, or become diffuse, leading to phase separation. The following effects are discussed: diffusion-induced phase separation, phase transitions occurring mainly due to the deformation-driven orientation of polymer chains and worm-like micelles that results in the formation of a liquid-crystal state, as well as self-assembly effects. It can be stressed that the appearance of regular structures takes place in systems that can coexist in different concentrations or phase states at the same stress or shear rate. This is linked with the existence of two-value points on flow curves (part of a flow curve with negative slope) or transient regimes of deformation that lead to instability of the flow. The described experimental facts are briefly discussed on the basis of the application of different constitutive molecular or phenomenological rheological models.