Literature DB >> 33630396

sp3 Bis-Organometallic Reagents via Catalytic 1,1-Difunctionalization of Unactivated Olefins.

Shang-Zheng Sun1,2, Laura Talavera1,2, Philipp Spieß1, Craig S Day1,2, Ruben Martin1,3.   

Abstract

A catalytic 1,1-difunctionalization of unactivated olefins en route to sp3 bis-organometallic B,B(Si)-reagents is described. The protocol is characterized by exceptional reaction rates, mild conditions, wide scope, and exquisite selectivity pattern, constituting a new platform to access sp3 bis-organometallics.
© 2021 Wiley-VCH GmbH.

Entities:  

Keywords:  Ni catalysis; bis-organometallic; chain-walking; olefin functionalization

Year:  2021        PMID： 33630396     DOI： 10.1002/anie.202100810

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction.

Authors:  Craig S Day; Cuong Dat Do; Carlota Odena; Jordi Benet-Buchholz; Liang Xu; Cina Foroutan-Nejad; Kathrin H Hopmann; Ruben Martin
Journal:  J Am Chem Soc       Date:  2022-07-13       Impact factor: 16.383

2.  Selective Coupling of 1,2-Bis-Boronic Esters at the more Substituted Site through Visible-Light Activation of Electron Donor-Acceptor Complexes.

Authors:  Hui Wang; Jingjing Wu; Adam Noble; Varinder K Aggarwal
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-07       Impact factor: 16.823

3.  Reductive Elimination from Sterically Encumbered Ni-Polypyridine Complexes.

Authors:  Craig S Day; Stephanie J Ton; Ryan T McGuire; Cina Foroutan-Nejad; Ruben Martin
Journal:  Organometallics       Date:  2022-09-21       Impact factor: 3.837
  3 in total

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