An enzyme-free electrochemiluminescence sensing probe based on ternary nanocomposite for ultrasensitive determination of chlorpyrifos.

Herein, an innovative enzyme free electrochemiluminescence chlorpyrifos sensor was reported based on the incorporation of ternary nanocomposite (ruthenium nanobeads/silver nanoparticles/graphene oxide) on the surface of glassy carbon electrode. The silver nanoparticles as a robust signal enhancing agent were well deposited on the modified graphene oxide/glassy carbon electrode and exhibited supreme electrocatalytic proficiency. Then, Ru(bipy)32+ species in bead-like nanoparticles were uniformly anchored on the surface of the modified electrode with the help of chitosan, as a good crosslinking agent. Boron nitride quantum dots as a new coreactant species showed the excellent proficiency for signal enhancement of the fabricated electrode. The fabricated electrode was successfully used as an ultra-sensitive sensor for trace analysis of chlorpyrifos by ECL technique. The wide linear range and the low detection limit were obtained from 5.0 × 10-15 to 4.2 × 10-9 M and 6.5 × 10-16 M, respectively.