Optical-Cavity Manipulation of Conical Intersections and Singlet Fission in Pentacene Dimers.

We demonstrate how the singlet fission process in pentacene dimers mediated by a conical intersection is controlled by coupling the molecule to a confined optical cavity photon mode. By following the polariton quantum dynamics of a conical intersection coupled to a cavity mode taking into account vibrational relaxation and cavity loss, we find that the singlet fission can be significantly suppressed because the polaritonic conical intersection is pushed away from the initial Franck-Condon excitation region.