Literature DB >> 33554998

On the mechanism of the formation of alkyl-Ni(I) catalysts.

M Teresa Quirós1, Daniel Collado-Sanz1, Elena Buñuel1, Diego J Cárdenas1.   

Abstract

The formation of catalytically active alkyl-Ni(i) complexes by comproportionation of diorgano-Ni(ii) precursors and Ni(0) species proceeds easily through triplet states by alkyl ligand exchange. The process involves inversion of the configuration at the carbon that is transferred.

Entities:  

Year:  2021        PMID: 33554998     DOI: 10.1039/d1cc00203a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Enantiomerically Enriched α-Borylzinc Reagents by Nickel-Catalyzed Carbozincation of Vinylboronic Esters.

Authors:  Chenlong Zhang; Weipeng Hu; Gabriel J Lovinger; Jing Jin; Jingjia Chen; James P Morken
Journal:  J Am Chem Soc       Date:  2021-08-23       Impact factor: 16.383

  1 in total

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