Literature DB >> 33546465

Synthesis of Bis{meso-Tetrakis(4-N-alkylpyridiniumyl)porphyrinato}cerium and Its Redox Switching Behavior.

Toshio Nishino1, Yasuyuki Yamada1,2,3, Ayumi Yamamoto1, Kentaro Tanaka1.   

Abstract

A novel double-decker porphyrin complex, bis{meso-tetrakis(4-N-alkylpyridiniumyl)porphyrinato}cerium, was prepared. Electrochemical measurements revealed that this complex exhibited reversible redox waves corresponding to a 1e- redox reaction of the cerium center. Treating the complex alternately with an oxidant and a reductant resulted in the reversible redox switching between the oxidized and reduced states in an organic solvent.

Entities:  

Keywords:  double-decker cerium complex; octacationic complex; redox switching

Mesh：

Substances：

Year:  2021        PMID： 33546465      PMCID： PMC7913613          DOI： 10.3390/molecules26040790

Source DB:  PubMed          Journal:  Molecules        ISSN： 1420-3049            Impact factor:   4.411


  26 in total

1.  A bevel-gear-shaped rotor bearing a double-decker porphyrin complex.

Authors:  Soichiro Ogi; Tomohiro Ikeda; Rie Wakabayashi; Seiji Shinkai; Masayuki Takeuchi
Journal:  Chemistry       Date:  2010-07-26       Impact factor: 5.236

2.  Arrays of double-decker porphyrins on highly oriented pyrolytic graphite.

Authors:  Joe Otsuki; Satoru Kawaguchi; Toshihisa Yamakawa; Masumi Asakawa; Koji Miyake
Journal:  Langmuir       Date:  2006-06-20       Impact factor: 3.882

3.  Synthesis, structure, spectroscopic properties, and electrochemistry of rare earth sandwich compounds with mixed 2,3-naphthalocyaninato and octaethylporphyrinato ligands.

Authors:  J Jiang; Y Bian; F Furuya; W Liu; M T Choi; N Kobayashi; H W Li; Q Yang; T C Mak; D K Ng
Journal:  Chemistry       Date:  2001-12-03       Impact factor: 5.236

4.  Tuning the valence of the cerium center in (Na)phthalocyaninato and porphyrinato cerium double-deckers by changing the nature of the tetrapyrrole ligands.

Authors:  Yongzhong Bian; Jianzhuang Jiang; Ye Tao; Michael T M Choi; Renjie Li; Anthony C H Ng; Peihua Zhu; Na Pan; Xuan Sun; Dennis P Arnold; Zhong-Yuan Zhou; Hung-Wing Li; Thomas C W Mak; Dennis K P Ng
Journal:  J Am Chem Soc       Date:  2003-10-08       Impact factor: 15.419

5.  A New Bis(phthalocyaninato) Terbium Single-Ion Magnet with an Overall Excellent Magnetic Performance.

Authors:  Yuxiang Chen; Fang Ma; Xiaoxiang Chen; Bowei Dong; Kang Wang; Shangda Jiang; Chiming Wang; Xin Chen; Dongdong Qi; Haoling Sun; Bingwu Wang; Song Gao; Jianzhuang Jiang
Journal:  Inorg Chem       Date:  2017-11-07       Impact factor: 5.165

6.  Probing the magnetic properties of three interconvertible redox states of a single-molecule magnet with magnetic circular dichroism spectroscopy.

Authors:  Mathieu Gonidec; E Stephen Davies; Jonathan McMaster; David B Amabilino; Jaume Veciana
Journal:  J Am Chem Soc       Date:  2010-02-17       Impact factor: 15.419

7.  Allosteric binding of an Ag+ ion to cerium(IV) bis-porphyrinates enhances the rotational activity of porphyrin ligands.

Authors:  Masato Ikeda; Masayuki Takeuchi; Seiji Shinkai; Fumito Tani; Yoshinori Naruta; Shigeru Sakamoto; Kentaro Yamaguchi
Journal:  Chemistry       Date:  2002-12-16       Impact factor: 5.236

8.  Supramolecular Approach for Enhancing Single-Molecule Magnet Properties of Terbium(III)-Phthalocyaninato Double-Decker Complexes with Crown Moieties.

Authors:  Yoji Horii; Shuhei Kishiue; Marko Damjanović; Keiichi Katoh; Brian K Breedlove; Markus Enders; Masahiro Yamashita
Journal:  Chemistry       Date:  2018-02-01       Impact factor: 5.236

9.  Changing Single-Molecule Magnet Properties of a Windmill-Like Distorted Terbium(III) α-Butoxy-Substituted Phthalocyaninato Double-Decker Complex by Protonation/Deprotonation.

Authors:  Yoji Horii; Yusuke Horie; Keiichi Katoh; Brian K Breedlove; Masahiro Yamashita
Journal:  Inorg Chem       Date:  2017-10-13       Impact factor: 5.165

10.  Observation and electric current control of a local spin in a single-molecule magnet.

Authors:  Tadahiro Komeda; Hironari Isshiki; Jie Liu; Yan-Feng Zhang; Nicolás Lorente; Keiichi Katoh; Brian K Breedlove; Masahiro Yamashita
Journal:  Nat Commun       Date:  2011       Impact factor: 14.919
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