| Literature DB >> 33544098 |
Merian Crumbach1, Ozan Ayhan1, Lars Fritze1, Jan A P Sprenger1, Ludwig Zapf1, Maik Finze1, Holger Helten1.
Abstract
Fully aromatic, luminescent, and highly robust BNB-doped phenalenyls have been prepared, which are isoelectronic to the phenalenyl cation. B-Fluoromesityl-substitution leads to fluorescence in an extremely narrow range and significant increase in the reduction potential. Detailed theoretical investigations revealed an intramolecular aromaticity switch upon one-electron reduction.Entities:
Year: 2021 PMID： 33544098 DOI： 10.1039/d0cc07671f
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222