The Influence of a Novel Hydrophobic Agent on the Internal Defect and Multi-Scale Pore Structure of Concrete.

In high humidity areas, it is necessary to improve the impermeability of concrete to water and other erosion solutions. The internal defect and pore channel of concrete are the main factors affecting the impermeability and durability. In this paper, a novel hydrophobic agent named Yellow River Engineering Consulting (YREC) was prepared. The relative internal defect degree of concrete with different curing ages and YREC contents was evaluated by ultrasonic non-destructive testing as qualitative characterization method, and the effect of YREC on hydration reaction was investigates using X-ray powder diffraction (XRD). Water permeability and contact angle tests were used to analyze the internal and external hydrophobicity induced by YREC addition, respectively. The pore structure changes of concrete mortar matrix induced by YREC were further discussed applying low-temperature liquid nitrogen adsorption (LT-NA) and mercury intrusion/extrusion porosimetry (MIP). The results indicated that YREC not only improves the impermeability of water, but also greatly enhances the mechanical strength. In the case of mixing YREC, the porosity of concrete mortar matrix decreases accompanied with the more advantage pores (micropores and transition pores) developed. Based on the relative internal defect degree and the changes of multi-scale pore structure, the functionality and durability of concrete with 4% YREC addition are the most desirable.