Literature DB >> 33520260

Ethyl 5-methyl-3-[11-(pyridin-2-yl)-6,11-di-hydro-6,11-ep-oxy-dibenzo[b,e]oxepin-6-yl]isoxazole-4-carboxylate: a bicyclic acetal from the rearrangement of an anthracenyl isoxazole.

Matthew J Weaver1, Michael J Campbell1, Chun Li2, Nicholas R Natale1.   

Abstract

The title compound, C26H20N2O5, is a rearrangement product of an o-pyridinyl anthracenyl isoxazole ester. It features a bicyclic acetal structure, which has two extended almost co-planar ring systems, which subtend a fold angle of 102.17 (5)°. In the crystal, the mol-ecules are closely knitted together through C-H⋯N and C-H⋯O hydrogen bonds and form chains of alternating enanti-omers propagating along the c-axis direction. © Weaver et al. 2020.

Entities:  

Keywords:  anthracenyl isoxazole; crystal structure; ep­oxy­dibenzo[b,e]oxepin; isoxazole

Year:  2020        PMID: 33520260      PMCID: PMC7784648          DOI: 10.1107/S2056989020014358

Source DB:  PubMed          Journal:  Acta Crystallogr E Crystallogr Commun


  1 in total

1.  Syntheses and crystal structures of a nitro-anthracene-isoxazole and its oxidation product.

Authors:  Chun Li; Matthew J Weaver; Michael J Campbell; Nicholas R Natale
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2022-06-10
  1 in total

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