Oleksandr V Kuznietsov1,2, George D Tsibidis3, Anatoliy V Demchishin4, Anatoliy A Demchishin4, Volodymyr Babizhetskyy5, Ivan Saldan5,6, Stefano Bellucci7, Iaroslav Gnilitskyi1,2. 1. NoviNano Lab LLC, Pasternaka 5, 79015 Lviv, Ukraine. 2. Department of Photonics, Lviv Polytechnic National University, 79013 Lviv, Ukraine. 3. Institute of Electronic Structure and Laser (IESL), Foundation for Research and Technology (FORTH), N. Plastira 100, Vassilika Vouton, 70013 Heraklion, Crete, Greece. 4. Frantsevich Institute for Problems in Materials Science of NASU, Krzhizhanovsky 3, 03142 Kyiv, Ukraine. 5. Faculty of Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodia 6, 79005 Lviv, Ukraine. 6. Faculty of Science, P.J. Šafárik University in Košice, Šrobárova 2, 04154 Košice, Slovakia. 7. INFN-Laboratori Nazionali di Frascati, Via E. Fermi 54, 00044 Frascati, Italy.
Abstract
2D Ti-Fe multilayer preparation has been attracting increased interest due to its ability to form intermetallic compounds between metallic titanium and metallic iron thin layers. In particular, the TiFe compound can absorb hydrogen gas at room temperature. We applied femtosecond laser pulses to heat Ti-Fe multilayer structures to promote the appearance of intermetallic compounds and generate surface nanostructuring. The surface pattern, known as Laser Induced Periodic Surface Structures (LIPSS), can accelerate the kinetics of chemical interaction between solid TiFe and gaseous hydrogen. The formation of LIPSS on Ti-Fe multilayered thin films were investigated using of scanning electron microscopy, photo-electron spectroscopy and X-ray diffraction. To explore the thermal response of the multiple layered structure and the mechanisms leading to surface patterning after irradiating the compound with single laser pulses, theoretical simulations were conducted to interpret the experimental observations.
2D <span cln class="Chemical">ass="Chemical">Ti-Fe multilayer preparation has been attracting increased interest due to its ability to form inter<ass="Chemical">span class="Chemical">metallic compounds between metallic titanium and metallic iron thin layers. In particular, the TiFecompound can absorb hydrogen gas at room temperature. We applied femtosecond laser pulses to heat Ti-Fe multilayer structures to promote the appearance of intermetallic compounds and generate surface nanostructuring. The surface pattern, known as Laser Induced Periodic Surface Structures (LIPSS), can accelerate the kinetics of chemical interaction between solid TiFe and gaseous hydrogen. The formation of LIPSS on Ti-Fe multilayered thin films were investigated using of scanning electron microscopy, photo-electron spectroscopy and X-ray diffraction. To explore the thermal response of the multiple layered structure and the mechanisms leading to surface patterning after irradiating the compound with single laser pulses, theoretical simulations were conducted to interpret the experimental observations.