Literature DB >> 33496569

Pt(II)-Decorated Covalent Organic Framework for Photocatalytic Difluoroalkylation and Oxidative Cyclization Reactions.

Zainab Almansaf1, Jiyun Hu1, Federica Zanca2, Hamid R Shahsavari1,3, Benjamin Kampmeyer1, Miu Tsuji1, Kartik Maity1, Valerie Lomonte1, Yumi Ha1, Piero Mastrorilli4, Stefano Todisco4, Mourad Benamara5, Rama Oktavian2, Arsalan Mirjafari6, Peyman Z Moghadam2, Ahmad R Khosropour1,7, Hudson Beyzavi1.   

Abstract

A new covalent organic framework (COF) based on imine bonds was assembled from 2-(4-formylphenyl)-5-formylpyridine and 1,3,6,8-tetrakis(4-aminophenyl)pyrene, which showed an interesting dual-pore structure with high crystallinity. Postmetallation of the COF with Pt occurred selectively at the N donor (imine and pyridyl) in the larger pores. The metallated COF served as an excellent recyclable heterogeneous photocatalyst for decarboxylative difluoroalkylation and oxidative cyclization reactions.

Entities:  

Keywords:  covalent organic framework; difluoroalkylation; oxidative cyclization; photocatalysis; platinum; reaction mechanism

Year:  2021        PMID： 33496569      PMCID： PMC7902083          DOI： 10.1021/acsami.0c21370

Source DB:  PubMed          Journal:  ACS Appl Mater Interfaces        ISSN： 1944-8244            Impact factor:   9.229


  44 in total

1.  3D Porphyrin-Based Covalent Organic Frameworks.

Authors:  Guiqing Lin; Huimin Ding; Rufan Chen; Zhengkang Peng; Baoshan Wang; Cheng Wang
Journal:  J Am Chem Soc       Date:  2017-06-15       Impact factor: 15.419

2.  Designed Synthesis of a 2D Porphyrin-Based sp2 Carbon-Conjugated Covalent Organic Framework for Heterogeneous Photocatalysis.

Authors:  Rufan Chen; Ji-Long Shi; Yuan Ma; Guiqing Lin; Xianjun Lang; Cheng Wang
Journal:  Angew Chem Int Ed Engl       Date:  2019-04-04       Impact factor: 15.336

3.  Towards covalent organic frameworks with predesignable and aligned open docking sites.

Authors:  Xiong Chen; Ning Huang; Jia Gao; Hong Xu; Fei Xu; Donglin Jiang
Journal:  Chem Commun (Camb)       Date:  2014-06-11       Impact factor: 6.222

4.  MOF-253-Supported Ru Complex for Photocatalytic CO2 Reduction by Coupling with Semidehydrogenation of 1,2,3,4-Tetrahydroisoquinoline (THIQ).

Authors:  Xiaoyu Deng; Yuhuan Qin; Mingming Hao; Zhaohui Li
Journal:  Inorg Chem       Date:  2019-11-27       Impact factor: 5.165

5.  Integrating Suitable Linkage of Covalent Organic Frameworks into Covalently Bridged Inorganic/Organic Hybrids toward Efficient Photocatalysis.

Authors:  Hou Wang; Cheng Qian; Jia Liu; Yongfei Zeng; Dongdong Wang; Weiqiang Zhou; Long Gu; Hongwei Wu; Guofeng Liu; Yanli Zhao
Journal:  J Am Chem Soc       Date:  2020-02-19       Impact factor: 15.419

6.  Covalent Organic Frameworks: Design, Synthesis, and Functions.

Authors:  Keyu Geng; Ting He; Ruoyang Liu; Sasanka Dalapati; Ke Tian Tan; Zhongping Li; Shanshan Tao; Yifan Gong; Qiuhong Jiang; Donglin Jiang
Journal:  Chem Rev       Date:  2020-01-22       Impact factor: 60.622

7.  A Covalent Organic Framework Bearing Single Ni Sites as a Synergistic Photocatalyst for Selective Photoreduction of CO2 to CO.

Authors:  Wanfu Zhong; Rongjian Sa; Liuyi Li; Yajun He; Lingyun Li; Jinhong Bi; Zanyong Zhuang; Yan Yu; Zhigang Zou
Journal:  J Am Chem Soc       Date:  2019-04-24       Impact factor: 15.419

Review 8.  Fluorine in pharmaceuticals: looking beyond intuition.

Authors:  Klaus Müller; Christoph Faeh; François Diederich
Journal:  Science       Date:  2007-09-28       Impact factor: 47.728

9.  Platinum(ii) photo-catalysis for highly selective difluoroalkylation reactions.

Authors:  Jian-Ji Zhong; Chen Yang; Xiao-Yong Chang; Chao Zou; Wei Lu; Chi-Ming Che
Journal:  Chem Commun (Camb)       Date:  2017-08-08       Impact factor: 6.222

10.  Construction of a Stable Ru-Re Hybrid System Based on Multifunctional MOF-253 for Efficient Photocatalytic CO2 Reduction.

Authors:  Xiaoyu Deng; Josep Albero; Lizhi Xu; Hermenegildo García; Zhaohui Li
Journal:  Inorg Chem       Date:  2018-07-02       Impact factor: 5.165
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  1 in total

1.  Aerobic Oxidative EDA Catalysis: Synthesis of Tetrahydroquinolines Using an Organocatalytic EDA Active Acceptor.

Authors:  August Runemark; Henrik Sundén
Journal:  J Org Chem       Date:  2022-01-10       Impact factor: 4.354
  1 in total

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