Literature DB >> 33479324

Dehydration of D-fructose to 5-hydroxymethyl-2-furfural in DMSO using a hydrophilic sulfonated silica catalyst in a process promoted by microwave irradiation.

Sandro L Barbosa1, Milton de S Freitas2, Wallans T P Dos Santos2, David Lee Nelson2, Stanlei I Klein3, Giuliano Cesar Clososki4, Franco J Caires4, Adriano C M Baroni5, Alexandre P Wentz6.   

Abstract

SiO2-SO3H, with a surface area of 115 m2/g, pore volumes of 0.38 cm3g-1 and 1.32 mmol H+/g, was used as a 10% w/w catalyst for the preparation of 5-hydroxymethyl-2-furfural (HMF) from fructose. A conversion of 100% was achieved in a microwave reactor during 10 min at 150 °C in DMSO, with 100% selectivity for HMF, at a molar ratio of fructose: DMSO equal to 1:56. The catalyst could be re-used three times.

Entities:  

Year:  2021        PMID: 33479324      PMCID: PMC7820282          DOI: 10.1038/s41598-020-80285-2

Source DB:  PubMed          Journal:  Sci Rep        ISSN: 2045-2322            Impact factor:   4.379


  9 in total

Review 1.  Ionic liquid-mediated formation of 5-hydroxymethylfurfural-a promising biomass-derived building block.

Authors:  Małgorzata E Zakrzewska; Ewa Bogel-Łukasik; Rafał Bogel-Łukasik
Journal:  Chem Rev       Date:  2010-10-25       Impact factor: 60.622

Review 2.  Chemical routes for the transformation of biomass into chemicals.

Authors:  Avelino Corma; Sara Iborra; Alexandra Velty
Journal:  Chem Rev       Date:  2007-05-30       Impact factor: 60.622

3.  Hydroxymethylfurfural, a versatile platform chemical made from renewable resources.

Authors:  Robert-Jan van Putten; Jan C van der Waal; Ed de Jong; Carolus B Rasrendra; Hero J Heeres; Johannes G de Vries
Journal:  Chem Rev       Date:  2013-02-11       Impact factor: 60.622

4.  Phase modifiers promote efficient production of hydroxymethylfurfural from fructose.

Authors:  Yuriy Román-Leshkov; Juben N Chheda; James A Dumesic
Journal:  Science       Date:  2006-06-30       Impact factor: 47.728

5.  Production of liquid alkanes by aqueous-phase processing of biomass-derived carbohydrates.

Authors:  George W Huber; Juben N Chheda; Christopher J Barrett; James A Dumesic
Journal:  Science       Date:  2005-06-03       Impact factor: 47.728

6.  Metal chlorides in ionic liquid solvents convert sugars to 5-hydroxymethylfurfural.

Authors:  Haibo Zhao; Johnathan E Holladay; Heather Brown; Z Conrad Zhang
Journal:  Science       Date:  2007-06-15       Impact factor: 47.728

7.  A one-pot reaction for biorefinery: combination of solid acid and base catalysts for direct production of 5-hydroxymethylfurfural from saccharides.

Authors:  Atsushi Takagaki; Mika Ohara; Shun Nishimura; Kohki Ebitani
Journal:  Chem Commun (Camb)       Date:  2009-09-07       Impact factor: 6.222

8.  Confinement Effects in Catalysis Using Well-Defined Materials and Cages.

Authors:  Valentinos Mouarrawis; Raoul Plessius; Jarl Ivar van der Vlugt; Joost N H Reek
Journal:  Front Chem       Date:  2018-12-21       Impact factor: 5.221

Review 9.  Recent Advances in the Microwave-Assisted Production of Hydroxymethylfurfural by Hydrolysis of Cellulose Derivatives-A Review.

Authors:  Frederic Delbecq; Christophe Len
Journal:  Molecules       Date:  2018-08-07       Impact factor: 4.411

  9 in total
  2 in total

1.  Catalytic Transformation of Triglycerides to Biodiesel with SiO2-SO3H and Quaternary Ammonium Salts in Toluene or DMSO.

Authors:  Sandro L Barbosa; Adeline C Pereira Rocha; David Lee Nelson; Milton S de Freitas; Antônio A P Fulgêncio Mestre; Stanlei I Klein; Giuliano C Clososki; Franco J Caires; Danilo L Flumignan; Letícia Karen Dos Santos; Alexandre P Wentz; Vânya M Duarte Pasa; Regiane D Fernandes Rios
Journal:  Molecules       Date:  2022-01-30       Impact factor: 4.411

2.  Tandem Transesterification-Esterification Reactions Using a Hydrophilic Sulfonated Silica Catalyst for the Synthesis of Wintergreen Oil from Acetylsalicylic Acid Promoted by Microwave Irradiation.

Authors:  Sandro L Barbosa; David Lee Nelson; Milton de S Freitas; Wallans Torres Pio Dos Santos; Stanlei I Klein; Giuliano C Clososki; Franco J Caires; Alexandre P Wentz
Journal:  Molecules       Date:  2022-07-26       Impact factor: 4.927

  2 in total

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