Nasim Danesh1, Mohsen Ghorbani2, Azam Marjani3,4. 1. Department of Chemistry, Arak Branch, Islamic Azad University, Arak, Iran. 2. Faculty of Chemical Engineering, Babol Noshirvani University of Technology, Shariati St., Babol, 4714871167, Iran. 3. Department for Management of Science and Technology Development, Ton Duc Thang University, Ho Chi Minh City, Viet Nam. azam.marjani@tdtu.edu.vn. 4. Faculty of Applied Sciences, Ton Duc Thang University, Ho Chi Minh City, Viet Nam. azam.marjani@tdtu.edu.vn.
Abstract
In this research, a novel nanocomposite adsorbent, graphene oxide modified with magnetite nanoparticles and Lauric acid containing ethylenediaminetetraacetic acid (GFLE) has been applied for the eliminate of Cu2+ ions. Adsorption performance was considered as a function of solution pH, Cu2+ ions concentration (C Cu2+), and temperature (T) and contact time (t). The levels of each variable were statistically optimized by Central Composite Design (CCD) and the response surface methodology (RSM) procedure to enhance the yield of system design. In these calculations, Y was measured as the response (the secondary concentration of Cu2+ ions in mg L-1). Highest copper adsorption occurred at time of 105 min, temperature of 40 °C, the initial concentration of 280 mg L-1, and pH = 1. The sorption equilibrium was well demonstrated using the Freundlich isotherm model. The second-order kinetics model suggested that the sorption mechanism might be ion exchange reactions. Thermodynamic factors and activation energy values displayed that the uptake process of Cu2+ ions was spontaneous, feasible, endothermic and physical in nature. Regeneration studies also revealed that GFLE could be consistently reused up to 3 cycles.
In this research, a novel nanocomposite n class="Chemical">adsorbent, graphene oxide modified with magnetite nanoparticles and Lauric acid containing ethylenediaminetetraacetic acid (GFLE) has been applied for the eliminate of Cu2+ ions. Adsorption performance was considered as a function of solution pH, Cu2+ ions concentration (C Cu2+), and temperature (T) and contact time (t). The levels of each variable were statistically optimized by Central Composite Design (CCD) and the response surface methodology (RSM) procedure to enhance the yield of system design. In these calculations, Y was measured as the response (the secondary concentration of Cu2+ ions in mg L-1). Highest copper adsorption occurred at time of 105 min, temperature of 40 °C, the initial concentration of 280 mg L-1, and pH = 1. The sorption equilibrium was well demonstrated using the Freundlich isotherm model. The second-order kinetics model suggested that the sorption mechanism might be ion exchange reactions. Thermodynamic factors and activation energy values displayed that the uptake process of Cu2+ ions was spontaneous, feasible, endothermic and physical in nature. Regeneration studies also revealed that GFLE could be consistently reused up to 3 cycles.