Literature DB >> 33447836

Tris-(2-pyridylmethyl)amine-ligated Cu(II) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives.

Josiah G D Elsberg1, Stephen N Anderson1, David L Tierney2, Eric W Reinheimer3, Lisa M Berreau1.   

Abstract

We report synthetic, structural and reactivity investigations of tris-(2-pyridylmethyl)amine (TPA)-ligated Cu(ii) 1,3-diketonate complexes. These complexes exhibit anaerobic retro-Claisen type C-C bond cleavage reactivity which exceeds that found in analogs supported by chelate ligands with fewer and/or weaker pyridyl interactions.

Entities:  

Year:  2021        PMID： 33447836      PMCID： PMC8174646          DOI： 10.1039/d0dt04074f

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  13 in total

1.  Oxygenation via C-H/C-C Bond Activation with Molecular Oxygen.

Authors:  Yu-Feng Liang; Ning Jiao
Journal:  Acc Chem Res       Date:  2017-06-21       Impact factor: 22.384

2.  Retrieval of crystallographically-derived molecular geometry information.

Authors:  Ian J Bruno; Jason C Cole; Magnus Kessler; Jie Luo; W D Sam Motherwell; Lucy H Purkis; Barry R Smith; Robin Taylor; Richard I Cooper; Stephanie E Harris; A Guy Orpen
Journal:  J Chem Inf Comput Sci       Date:  2004 Nov-Dec

3.  Cu-catalyzed esterification reaction via aerobic oxygenation and C-C bond cleavage: an approach to α-ketoesters.

Authors:  Chun Zhang; Peng Feng; Ning Jiao
Journal:  J Am Chem Soc       Date:  2013-09-26       Impact factor: 15.419

4.  First row divalent transition metal complexes of aryl-appended tris((pyridyl)methyl)amine ligands: syntheses, structures, electrochemistry, and hydroxamate binding properties.

Authors:  Magdalena M Makowska-Grzyska; Ewa Szajna; Crystal Shipley; Atta M Arif; Michael H Mitchell; Jason A Halfen; Lisa M Berreau
Journal:  Inorg Chem       Date:  2003-11-17       Impact factor: 5.165

5.  Mono-, bi-, and trinuclear CuII-Cl containing products based on the tris(2-pyridylmethyl)amine chelate derived from copper(I) complex dechlorination reactions of chloroform.

Authors:  Baldo Lucchese; Kristi J Humphreys; Dong-Heon Lee; Christopher D Incarvito; Roger D Sommer; Arnold L Rheingold; Kenneth D Karlin
Journal:  Inorg Chem       Date:  2004-09-20       Impact factor: 5.165

6.  Anion Effects in Oxidative Aliphatic Carbon-Carbon Bond Cleavage Reactions of Cu(II) Chlorodiketonate Complexes.

Authors:  Sushma L Saraf; Anna Miłaczewska; Tomasz Borowski; Christopher D James; David L Tierney; Marina Popova; Atta M Arif; Lisa M Berreau
Journal:  Inorg Chem       Date:  2016-07-05       Impact factor: 5.165

7.  Suggestion of an organometallic intermediate in an intramolecular dechlorination reaction involving copper(I) and a ArCH2Cl moiety.

Authors:  Debabrata Maiti; Amy A Narducci Sarjeant; Shinobu Itoh; Kenneth D Karlin
Journal:  J Am Chem Soc       Date:  2008-04-05       Impact factor: 15.419

8.  Reductive coupling of nitrogen monoxide (*NO) facilitated by heme/copper complexes.

Authors:  Jun Wang; Mark P Schopfer; Simona C Puiu; Amy A N Sarjeant; Kenneth D Karlin
Journal:  Inorg Chem       Date:  2010-02-15       Impact factor: 5.165

9.  SHELXT - integrated space-group and crystal-structure determination.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A Found Adv       Date:  2015-01-01       Impact factor: 2.290

10.  Crystal structure refinement with SHELXL.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr C Struct Chem       Date:  2015-01-01       Impact factor: 1.172
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