Crosslinking Dependence of Direct Current Breakdown Performance for XLPE-PS Composites at Different Temperatures.

In this paper, crosslinked polyethylene-polystyrene (XLPE-PS) composites with different degrees of crosslinking were fabricated by using different crosslinking agent contents and their direct current (DC) breakdown performance at 30~90 °C was investigated. Results show that with the increase of the degree of crosslinking, the crystallinity of XLPE-PS composites decreases gradually, but their DC breakdown strength demonstrates an increasing trend at 30~90 °C and the enhancement also increases with the rise of temperature. And as the degree of crosslinking increases, the elastic modulus of XLPE-PS composites is reduced and the loss tangent peak temperature decreases but the peak shifts to a lower value, which reveals the suppression of the relaxation process for crystallites. It is believed that high DC breakdown strength with good temperature stability for XLPE-PS composites with a larger degree of crosslinking is attributable to the presence of PS and suppression in the formation of crystallites due to crosslinking.