Literature DB >> 33431681

Stone-Wales defects preserve hyperuniformity in amorphous two-dimensional networks.

Duyu Chen1, Yu Zheng2, Lei Liu3, Ge Zhang4, Mohan Chen5, Yang Jiao6,2, Houlong Zhuang7.   

Abstract

Disordered hyperuniformity (DHU) is a recently discovered novel state of many-body systems that possesses vanishing normalized infinite-wavelength density fluctuations similar to a perfect crystal and an amorphous structure like a liquid or glass. Here, we discover a hyperuniformity-preserving topological transformation in two-dimensional (2D) network structures that involves continuous introduction of Stone-Wales (SW) defects. Specifically, the static structure factor [Formula: see text] of the resulting defected networks possesses the scaling [Formula: see text] for small wave number k, where [Formula: see text] monotonically decreases as the SW defect concentration p increases, reaches [Formula: see text] at [Formula: see text], and remains almost flat beyond this p. Our findings have important implications for amorphous 2D materials since the SW defects are well known to capture the salient feature of disorder in these materials. Verified by recently synthesized single-layer amorphous graphene, our network models reveal unique electronic transport mechanisms and mechanical behaviors associated with distinct classes of disorder in 2D materials.

Entities:  

Keywords:  2D materials; Stone–Wales transformation; disordered hyperuniformity

Year:  2021        PMID: 33431681      PMCID: PMC7826391          DOI: 10.1073/pnas.2016862118

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   12.779


  50 in total

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