Literature DB >> 33389561

A review on various aspects of organic synthesis using Comins' reagent.

Duraipandi Devi Priya1, Chetan Lakshman1, Selvaraj Mohana Roopan2.   

Abstract

Recently, researchers have shown great interest in compounds such as triflate and enotriflate that are synthesized by Comins reagent. For the above-mentioned reason, we planned to review the works related to organic synthesis using Comins reagent. So this review includes a whole new investigation of the Comins reagent which is used for stereoselective conversion of α-keto ester, enolate to enol triflate of lactone and vinyl triflate to methyl ketone. Comins reagent plays an important role in regioselectivity such as transformations of ketone or dienolates into vinyl triflates and it has a major application in highly selective oxidation in an easy and environmentally friendly manner.
© 2021. The Author(s), under exclusive licence to Springer Nature Switzerland AG part of Springer Nature.

Entities:  

Keywords:  Comins reagent; Coupling; Deoxydation; Stereoselective reagent; Triflating agent

Mesh：

Substances：

Year:  2021        PMID： 33389561     DOI： 10.1007/s11030-020-10175-2

Source DB:  PubMed          Journal:  Mol Divers        ISSN： 1381-1991            Impact factor:   2.943


  20 in total

1.  Toward a general route to the eunicellin diterpenes: the asymmetric total synthesis of deacetoxyalcyonin acetate.

Authors:  Gary A Molander; David J St Jean; Julia Haas
Journal:  J Am Chem Soc       Date:  2004-02-18       Impact factor: 15.419

2.  Stereocontrolled synthesis of the sterically encumbered F ring of lancifodilactone G.

Authors:  Kwong Wah Lai; Leo A Paquette
Journal:  Org Lett       Date:  2008-05-03       Impact factor: 6.005

3.  Total synthesis of (-)-laulimalide.

Authors:  Paul A Wender; Sayee G Hegde; Robert D Hubbard; Lei Zhang
Journal:  J Am Chem Soc       Date:  2002-05-08       Impact factor: 15.419

4.  Synthesis and Further Reactivity of Functionalized Lactam-Derived Enol Triflates.

Authors:  Tim Luker; Henk Hiemstra; W. Nico Speckamp
Journal:  J Org Chem       Date:  1997-11-14       Impact factor: 4.354

5.  Rapid Construction of the ABCE Tetracyclic Tertiary Amine Skeleton in Daphenylline Enabled by an Amine-Borane Complexation Strategy.

Authors:  Meng Deng; Yanmin Yao; Xiaohu Li; Nan Li; Xiao Zhang; Guangxin Liang
Journal:  Org Lett       Date:  2019-04-22       Impact factor: 6.005

6.  Asymmetric total synthesis of caribenol A via an intramolecular Diels-Alder reaction.

Authors:  Jing-Chun Han; Lian-Zhu Liu; Yuan-Yuan Chang; Guo-Zong Yue; Jie Guo; Li-Yan Zhou; Chuang-Chuang Li; Zhen Yang
Journal:  J Org Chem       Date:  2013-05-23       Impact factor: 4.354

7.  Catalytic asymmetric synthesis of quaternary carbons bearing two aryl substituents. Enantioselective synthesis of 3-alkyl-3-aryl oxindoles by catalytic asymmetric intramolecular heck reactions.

Authors:  Amy B Dounay; Keiko Hatanaka; Jeremy J Kodanko; Martin Oestreich; Larry E Overman; Lance A Pfeifer; Matthew M Weiss
Journal:  J Am Chem Soc       Date:  2003-05-21       Impact factor: 15.419

8.  Benzopyrans as selective estrogen receptor beta agonists (SERBAs). Part 5: Combined A- and C-ring structure-activity relationship studies.

Authors:  Timothy I Richardson; Jeffrey A Dodge; Yong Wang; Jim D Durbin; Venkatesh Krishnan; Bryan H Norman
Journal:  Bioorg Med Chem Lett       Date:  2007-08-11       Impact factor: 2.823

9.  Combined C-H activation/cope rearrangement as a strategic reaction in organic synthesis: total synthesis of (-)-colombiasin a and (-)-elisapterosin B.

Authors:  Huw M L Davies; Xing Dai; Matthew S Long
Journal:  J Am Chem Soc       Date:  2006-02-22       Impact factor: 15.419

10.  New strategy for convergent steroid synthesis.

Authors:  Olivier Lepage; Pierre Deslongchamps
Journal:  J Org Chem       Date:  2003-03-21       Impact factor: 4.354
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