Enhanced adsorptive removal of sulfamethoxazole from water using biochar derived from hydrothermal carbonization of sugarcane bagasse.

This research work primarily focussed on the production of biochar from sugarcane bagasse through HTC followed by NaOH activation at inert atmosphere for removing SMX from water. The biochar was characterized for structural morphology and presence of functional groups. XRD and FTIR analysis confirmed that presence of aromatized graphitic structure accumulated with oxygenated functional groups are responsible for the elimination of SMX. SEM analysis portrayed the sphere-shaped structure of biochar with hydrophobic groups interior and hydrophilic groups exterior. BET isotherm revealed the active surface area equal to 1099 m2/g with high coverage of mesopores structure. Pzpc of adsorbent is evaluated to 6.5 stating that effective removal of SMX depends on ionization effects induced due to reaction medium. Kinetics study revealed the sorption of SMX followed chemical interaction pertaining to Elovich model. Isotherm studies revealed that Freundlich model fitted well stating heterogeneous mode of interaction. Immobilization of SMX on surface of ABC is due to charge assisted hydrogen bonding and π-π interaction with graphitized carbon, showing maximum sorption capacity of 400 mg/g through spontaneous reaction. The results suggested that HTC derived biochar had great adsorption affinity with respect to pH towards SMX and could be employed as an effective sorbent in cleaning water contaminants.