Top-Down Direct Preparation of Orange-Yellow Dye Similar to Psittacofulvins from Commercial Polymer by Laser Writing.

Laser manufacturing is a promising method for the design and preparation of high value-added materials. When the laser acts on the polymer precursors, some wonderful phenomena will always occur and accompanied by the generation of new substances. Herein, we report a top-down approach for the direct preparation of orange-yellow dye that is similar to psittacofulvins from commercial polymer resins by laser writing. Conjugated double bonds and micro-rough structures are formed simultaneously on laser-irradiated polymer substrate surfaces. The typical polyconjugated structures of psittacofulvin dyes were confirmed by micro-Raman and Raman imaging results. Temperature-dependent Fourier transform infrared and X-ray photoelectron spectroscopy further demonstrated the formation mechanism of laser-induced psittacofulvins dyes based on the chemical composition. Further, optical microscopy, laser confocal microscopy, and scanning electron microscopy were carried out to characterize the physical morphologies of laser-irradiated polymer substrates. A unique advantage of preparing psittacofulvins dye using laser writing is its simple steps, and the dye can be converted directly from the appropriate precursor substrate. Interestingly, the laser-irradiated polymer substrate surface undergoes color change. This laser-induced color patterning is attractive due to the characteristics of high precision, flexibility, and maskless; any patterns can be easily designed and produced on the polymer at desired positions.