The construction of a single-crystalline SbSI nanorod array-WO3 heterostructure photoanode for high PEC performance.

A novel kind of highly efficient photoanode was constructed with a SbSI/WO3 heterostructurefabricated through two hydrothermal reactions followed by an iodination reaction (WO3 → Sb2S3/WO3 → SbSI/WO3). After optimizing the solvent [carbon disulfide (CS2)] for SbI3, the SbSI(CS2)/WO3 photoanode shows high-density single-crystalline SbSI nanorods growing along the polar [001] direction on WO3 nanoplates, resulting in excellent photocurrent performance (∼2.1 mA cm-2@1.23 V vs. RHE) and an improved photostability. It is evidenced that the higher crystallinity of SbSI has a positive effect on the photostability of the constructed SbSI/WO3 photoanodes.