Literature DB >> 33283802

Bulk ionic screening lengths from extremely large-scale molecular dynamics simulations.

Johannes Zeman1, Svyatoslav Kondrat2, Christian Holm1.   

Abstract

Recent experiments have reported anomalously large screening lengths of interactions between charged surfaces confining concentrated electrolytes and ionic liquids. Termed underscreening, this effect was ascribed to bulk properties of dense ionic systems. Herein, we study bulk ionic screening with extremely large-scale molecular dynamics simulations, allowing us to assess the range of distances relevant to the experiments. Our results yield two screening lengths satisfying distinct scaling relations. However, with an accuracy of 10-5 kBT in interionic potentials of mean force, we find no signs of underscreening, suggesting that other than bulk effects might be at play in the experiments.

Year:  2020        PMID: 33283802     DOI: 10.1039/d0cc05023g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Colloidal Systems in Concentrated Electrolyte Solutions Exhibit Re-entrant Long-Range Electrostatic Interactions due to Underscreening.

Authors:  Haiyang Yuan; Wenjie Deng; Xiaolong Zhu; Guangming Liu; Vincent Stuart James Craig
Journal:  Langmuir       Date:  2022-05-05       Impact factor: 4.331

2.  Mesoscopic Inhomogeneities in Concentrated Electrolytes.

Authors:  Oksana Patsahan; Alina Ciach
Journal:  ACS Omega       Date:  2022-02-16
  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.