Efficient removal of norfloxacin in water using magnetic molecularly imprinted polymer.

Effective and practical materials are important for the pollution control in the environment. A novel magnetic molecularly imprinted polymer (CoFe2O4@TiO2-MMIP) was prepared based on the surface molecular imprinting technology combined with photocatalytic degradation and magnetic separation. The adsorption rate constant and maximum adsorption capacity of CoFe2O4@TiO2-MMIP are 0.21 g mg-1 min-1 and 14.26 mg g-1, respectively. The effects of experimental factors on the adsorption properties of the magnetic molecularly imprinted polymer were investigated. CoFe2O4@TiO2-MMIP had selective adsorption ability towards fluoroquinolones. The adsorption efficiency was closely related to the molecular structure, molecular weight, polarity and functional groups of the target contaminant and the removal efficiency of norfloxacin was affected by another substance obviously in binary adsorption system. The adsorption-photocatalytic recycling experiment verified that CoFe2O4@TiO2-MMIP could simultaneously complete the degradation of pollutants and in-situ regeneration, indicating good reusability. This material with selective adsorption and photocatalytic regeneration would have substantial attraction for application in the removal of fluoroquinolones.