Literature DB >> 33164012

Strategies and mechanisms of metal-ligand cooperativity in first-row transition metal complex catalysts.

Matthew R Elsby1, R Tom Baker.   

Abstract

The use of metal-ligand cooperation (MLC) by transition metal bifunctional catalysts has emerged at the forefront of homogeneous catalysis science. Specially designed ligands can serve a Lewis base or Lewis acid function, as an aromatization/dearomatization shuttle, or as an electron reservoir with reversible redox activity. This review encapsulates advances that have been made in this field over the last ten years, focusing exclusively on first-row transition metals, and highlighting significant contributions to mechanistic understanding.

Entities:  

Year:  2020        PMID： 33164012     DOI： 10.1039/d0cs00509f

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN： 0306-0012            Impact factor:   54.564


  12 in total

Review 1.  Heteroligand Metal Complexes with Extended Redox Properties Based on Redox-Active Chelating Ligands of o-Quinone Type and Ferrocene.

Authors:  Svetlana V Baryshnikova; Andrey I Poddel'sky
Journal:  Molecules       Date:  2022-06-19       Impact factor: 4.927

2.  Aerobic Oxidation Reactivity of Well-Defined Cobalt(II) and Cobalt(III) Aminophenol Complexes.

Authors:  Jiaqi Liu; Shannen C Lorraine; Brian S Dolinar; Jessica M Hoover
Journal:  Inorg Chem       Date:  2022-04-12       Impact factor: 5.436

Review 3.  Homogeneous Carbon Capture and Catalytic Hydrogenation: Toward a Chemical Hydrogen Battery System.

Authors:  Duo Wei; Rui Sang; Ayeshe Moazezbarabadi; Henrik Junge; Matthias Beller
Journal:  JACS Au       Date:  2022-04-29

4.  Tuning Ruthenium Carbene Complexes for Selective P-H Activation through Metal-Ligand Cooperation.

Authors:  Kai-Stephan Feichtner; Lennart T Scharf; Thorsten Scherpf; Bert Mallick; Nils Boysen; Viktoria H Gessner
Journal:  Chemistry       Date:  2021-11-11       Impact factor: 5.020

5.  Acceptorless Dehydrogenation of Methanol to Carbon Monoxide and Hydrogen using Molecular Catalysts.

Authors:  Akash Kaithal; Basujit Chatterjee; Christophe Werlé; Walter Leitner
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-16       Impact factor: 16.823

6.  Just Add Water: Modulating the Structure-Derived Acidity of Catalytic Hexameric Resorcinarene Capsules.

Authors:  David A Poole; Simon Mathew; Joost N H Reek
Journal:  J Am Chem Soc       Date:  2021-09-30       Impact factor: 15.419

7.  Combining metal-metal cooperativity, metal-ligand cooperativity and chemical non-innocence in diiron carbonyl complexes.

Authors:  Cody B van Beek; Nicolaas P van Leest; Martin Lutz; Sander D de Vos; Robertus J M Klein Gebbink; Bas de Bruin; Daniël L J Broere
Journal:  Chem Sci       Date:  2022-01-18       Impact factor: 9.825

Review 8.  Sustainable catalysis with fluxional acridine-based PNP pincer complexes.

Authors:  Sayan Kar; David Milstein
Journal:  Chem Commun (Camb)       Date:  2022-03-18       Impact factor: 6.222

9.  Cooperative C-H Bond Activation by a Low-Spin d6 Iron-Aluminum Complex.

Authors:  Nikolaus Gorgas; Andrew J P White; Mark R Crimmin
Journal:  J Am Chem Soc       Date:  2022-05-05       Impact factor: 16.383

10.  Cooperative B-H bond activation: dual site borane activation by redox active κ2-N,S-chelated complexes.

Authors:  Mohammad Zafar; Asif Ahmad; Suvam Saha; Rongala Ramalakshmi; Thierry Roisnel; Sundargopal Ghosh
Journal:  Chem Sci       Date:  2022-06-23       Impact factor: 9.969
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