High-resolution infrared action spectroscopy of the fundamental vibrational band of CN.

Rotational-vibrational transitions of the fundamental vibrational modes of the 12C14N+ and 12C15N+ cations have been observed for the first time using a cryogenic ion trap apparatus with an action spectroscopy scheme. The lines P(3) to R(3) of 12C14N+ and R(1) to R(3) of 12C15N+ have been measured, limited by the trap temperature of approximately 4 K and the restricted tuning range of the infrared laser. Spectroscopic parameters are presented for both isotopologues, with band origins at 2000.7587(1) and 1970.321(1) cm-1, respectively, as well as an isotope independent fit combining the new and the literature data.